Transition Metal-Free trans-Selective Alkynylboration of Alkynes

Jacs
Transition Metal-Free trans-Selective Alkynylboration of Alkynes: We report the first transition metal-free and trans-selective alkynylboration reaction of alkynes. This unprecedented carboboration reaction is enabled by pseudo-intramolecular activation of alkynylboronates using propargylic alcohols. 

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