Synthesis of the Epimeric Secosteroids Strophasterols A and B

Angewchem
Synthesis of the Epimeric Secosteroids Strophasterols A and B: Two epimeric rearranged ergostanes, strophasterols A and B, with an unprecedented carbon skeleton were synthesized from ergosterol, both in 17 steps via a common secosteroidal intermediate. The conversion...

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