Synthesis and Reactivity of Fluoroalkyl Copper Complexes by the Oxycupration of Tetrafluoroethylene

Angewchem
Synthesis and Reactivity of Fluoroalkyl Copper Complexes by the Oxycupration of Tetrafluoroethylene: The copper(I)‐mediated generation of ‐OCF2CF2‐ moieties by the oxycupration of tetrafluoroethylene (TFE) using either copper aryloxides or alkoxides is disclosed. The key intermediates, 2‐aryloxy‐1,1,2,2‐tetrafluoroethyl...

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