Selective Si−C(sp3) Bond Cleavage in (Aminomethyl)silanes by Carbanionic Nucleophiles and Its Stereochemical Course

Angewchem
Selective Si−C(sp3) Bond Cleavage in (Aminomethyl)silanes by Carbanionic Nucleophiles and Its Stereochemical Course: Selective cleavage of a silicon–carbon bond in tetraorganosilanes is still a great challenge. A new type of Si−C(sp3) bond cleavage in bench‐stable (aminomethyl)silanes with common organolithium reagents...

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