Ring‐Opening 1‐Amino‐3‐aminomethylation of Donor–Acceptor Cyclopropanes via 1,3‐Diazepanes

Angewchem
Ring‐Opening 1‐Amino‐3‐aminomethylation of Donor–Acceptor Cyclopropanes via 1,3‐Diazepanes: The first ring‐opening reaction of donor–acceptor cyclopropanes to give diamines is reported. For this reaction, a 1,3‐bisfunctionalization was developed using cyclopropanes, triazinanes, and Sc(OTf)3...

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