Rhodium‐Catalyzed Enantioselective Radical Addition of CX4 Reagents to Olefins

Angewchem
Rhodium‐Catalyzed Enantioselective Radical Addition of CX4 Reagents to Olefins: We describe the synthetically useful enantioselective addition of Br−CX3 (X=Cl or Br) to terminal olefins to introduce a trihalomethyl group and generate optically active secondary bromides. Computational...

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