(NHC)NiH‐Catalyzed Intermolecular Regio‐ and Diastereoselective Cross‐Hydroalkenylation of Endocyclic Dienes with α‐Olefins

Angewchem
(NHC)NiH‐Catalyzed Intermolecular Regio‐ and Diastereoselective Cross‐Hydroalkenylation of Endocyclic Dienes with α‐Olefins: Highly selective cross‐hydroalkenylations of endocyclic 1,3‐dienes at the least substituted site with α‐olefins were achieved with a set of neutral (NHC)NiIIH(OTf) catalysts and cationic NiII catalysts...

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