Dynamic Kinetic Resolution of Allylic Azides via Asymmetric Dihydroxylation

Jacs
Dynamic Kinetic Resolution of Allylic Azides via Asymmetric Dihydroxylation: The catalytic enantioselective preparation of densely functionalized amines is a fundamental synthetic challenge. To address this challenge, we report for the first time that the Winstein rearrangement can be enlisted as the racemization pathway in a dynamic kinetic resolution of allylic azides.

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