Total Synthesis of a Dimeric Thymol Derivative Isolated from Arnica sachalinensis

Angewchem
Total Synthesis of a Dimeric Thymol Derivative Isolated from Arnica sachalinensis: The total synthesis of a dimeric thymol derivative (thymarnicol) isolated from Arnica sachalinensis was accomplished in 6 steps. A key biomimetic Diels–Alder dimerization was found to occur at ambient temperature and the final oxidative cyclization occurs when the substrate is exposed to air and visible light.

No comments:

Post a Comment

Popular Posts