Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide

Nature 545, 84–88 (04 May 2017) doi:10.1038/nature22316Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide
Francisco Juliá-Hernández, Toni Moragas, Josep Cornella & Ruben Martin
A nickel catalyst that promotes carboxylation of halogenated hydrocarbons at remote aliphatic sites with carbon dioxide via tunable and controllable chain-walking is described.


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