Nickel-Catalyzed Reductive Dicarbofunctionalization of Alkenes

Jacs
Nickel-Catalyzed Reductive Dicarbofunctionalization of Alkenes: An intermolecular, three-component reductive dicarbofunctionalization of alkenes is presented here. The combination of Ni catalysis with TDAE as final reductant enables the direct formation of Csp3–Csp3 and Csp3–Csp2 bonds across a variety of π-systems using two different electrophiles that are sequentially activated with exquisite selectivity under mild reaction conditions.

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