Iterative assembly line synthesis of polypropionates with full stereocontrol

Naturechem
Iterative assembly line synthesis of polypropionates with full stereocontrol
Teerawut Bootwicha, Julian M. Feilner, Eddie L. Myers & Varinder K. Aggarwal
Cross coupling under transition-metal-free conditions is an attractive and economic alternative to traditional transition metal-catalysed methods. Metal-free coupling of azaallyls has now been demonstrated with vinyl bromide electrophiles, delivering allylic amines in excellent yields. Moreover, mechanistic evidence supports dual reaction pathways triggered by azaallyl anions and radicals.

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