Mizoroki–Heck Cyclizations of Amide Derivatives for the Introduction of Quaternary Centers

Angewchem
Mizoroki–Heck Cyclizations of Amide Derivatives for the Introduction of Quaternary Centers: We report non‐decarbonylative Mizoroki–Heck reactions of amide derivatives. The transformation relies on the use of nickel catalysis and proceeds using sterically hindered tri‐ and tetrasubstituted olefins to give products containing quaternary centers.

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