Manganese(I)‐Catalyzed Regioselective C−H Allenylation: Direct Access to 2‐Allenylindoles

Angewchem
Manganese(I)‐Catalyzed Regioselective C−H Allenylation: Direct Access to 2‐Allenylindoles: A MnI‐catalyzed regioselective C−H allenylation is reported that allows a broad range of 2‐allenylindoles to be synthesized regioselectively on a gram scale under simple conditions. Notably, a highly efficient chirality transfer was observed (up to 93 % ee) in this transformation.

No comments:

Post a Comment

Popular Posts