Direct Nucleophilic Substitution Reaction of Cage B−H Bonds by Grignard Reagents: A Route to Regioselective B4‐Alkylation of o‐Carboranes

Angewchem
Direct Nucleophilic Substitution Reaction of Cage B−H Bonds by Grignard Reagents: A Route to Regioselective B4‐Alkylation of o‐Carboranes: Direct nucleophilic substitution reaction of cage B−H bonds of o‐carboranes by Grignard reagents in the absence of any transition metals has been achieved for the first time, and leads to the regioselective...

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