C−N Bond Activation and Ring Opening of a Saturated N‐Heterocyclic Carbene by Lateral Alkali‐Metal‐Mediated Metalation

Angewchem
C−N Bond Activation and Ring Opening of a Saturated N‐Heterocyclic Carbene by Lateral Alkali‐Metal‐Mediated Metalation: Combining alkali‐metal‐mediated metalation (AMMM) and N‐heterocyclic carbene (NHC) chemistry, a novel C−N bond activation and ring‐opening process is described for these increasingly important NHC molecules,...

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