Palladium(II)-Catalyzed Directed anti-Hydrochlorination of Unactivated Alkynes with HCl - Journal of the American Chemical Society (ACS Publications)

Palladium(II)-Catalyzed Directed anti-Hydrochlorination of Unactivated Alkynes with HCl - Journal of the American Chemical Society (ACS Publications)
A regioselective anti-hydrochlorination of unactivated alkynes is reported. The reaction utilizes in situ generated HCl as the source of both the Cl and H+ and is catalyzed by palladium(II) acetate, with loadings as low as 25 ppm.
 

Comments

Popular posts from this blog

Selective Metal‐free HB(C6F5)2 Catalyzed Allene Cyclotrimerization: Formation of 1,3,5‐Trimethylenecyclohexane and Its Tris‐hydroboration Product