Palladium‐Catalyzed Asymmetric Construction of Vicinal Tertiary and All‐Carbon Quaternary Stereocenters by Allylation of β‐Ketocarbonyls with Morita–Baylis–Hillman Adducts

Angewchem
Palladium‐Catalyzed Asymmetric Construction of Vicinal Tertiary and All‐Carbon Quaternary Stereocenters by Allylation of β‐Ketocarbonyls with Morita–Baylis–Hillman Adducts: Palladium‐catalyzed regio‐, diastereo‐, and enantioselective allylic alkylation of β‐ketocarbonyls with Morita–Baylis–Hillman adducts has been developed using a spiroketal‐based diphosphine (SKP) as the...

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