Base‐Controlled Completely Selective Linear or Branched Rhodium(I)‐Catalyzed C−H ortho‐Alkylation of Azines without Preactivation

Angewchem
Base‐Controlled Completely Selective Linear or Branched Rhodium(I)‐Catalyzed C−H ortho‐Alkylation of Azines without Preactivation: A [RhI]/bisphosphine/base catalytic system for the ortho‐selective C−H alkylation of azines by acrylates and acrylamides is reported. This catalytic system features an unprecedented complete linear or branched selectivity that is solely dependent on the catalytic base that is used.

No comments:

Post a Comment

Popular Posts