Water as a Hydride Source in Palladium‐Catalyzed Enantioselective Reductive Heck Reactions

Angewchem
Water as a Hydride Source in Palladium‐Catalyzed Enantioselective Reductive Heck Reactions: Pd‐catalyzed intramolecular asymmetric carbopalladation of N‐aryl acrylamides followed by reduction of C(sp3)‐Pd intermediate using diboron–water as a hydride source afforded enantioenriched 3,3‐disubstituted...

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