Metal‐Free Intermolecular Aminoarylation of Alkynes

Angewchem
Metal‐Free Intermolecular Aminoarylation of Alkynes: A metal‐free aminoarylation of internal alkynes is described, yielding tetrasubstituted enaminoates. The transformation proceeds in good to excellent yields through a tandem conjugate addition/Smiles rearrangement...

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