Fluorinated Sulfilimino Iminiums: Efficient and Versatile Sources of Perfluoroalkyl Radicals under Photoredox Catalysis

Angewchem
Fluorinated Sulfilimino Iminiums: Efficient and Versatile Sources of Perfluoroalkyl Radicals under Photoredox Catalysis: Reported herein is the use of S‐perfluoroalkyl sulfilimino iminiums as a new source of RF radicals under visible‐light photoredox catalysis (RF=CF3, C4F9, CF2Br, CFCl2). These shelf‐stable perfluoroalkyl...

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