Unified Total Synthesis of Madangamines A, C, and E - Journal of the American Chemical Society (ACS Publications)

Unified Total Synthesis of Madangamines A, C, and E - Journal of the American Chemical Society (ACS Publications)
A stereodivergent strategy for the synthesis of skipped dienes is developed. The method consists of hydroboration of allenes and Migita–Kosugi–Stille coupling, which allows for access to all four possible stereoisomers of the skipped dienes. 

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