Selective Arene Cleavage by Direct Insertion of Iridium into the Aromatic Ring

Selective Arene Cleavage by Direct Insertion of Iridium into the Aromatic Ring: We report an unprecedented selective cleavage of aromatic C−C bonds through the insertion of well‐defined iridium complexes into the aromatic ring of simple alkylarenes. The insertion occurs at 50–100 °C...

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