Rethinking the Claisen–Tishchenko Reaction

Rethinking the Claisen–Tishchenko Reaction: Pincer‐type complexes [OsH2(CO){PyCH2NHCH2CH2NHPtBu2}] and [OsH2(CO){HN(CH2CH2PiPr2)2}] catalyze the disproportionation reaction of aldehydes via an outer‐sphere bifunctional mechanism achieving turnover...

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