Highly Regio- and Enantioselective Vicinal Dihalogenation of Allyl Amides - Journal of the American Chemical Society (ACS Publications)

Highly Regio- and Enantioselective Vicinal Dihalogenation of Allyl Amides - Journal of the American Chemical Society (ACS Publications)
We report a highly regio-, diastereo- and enantioselective vicinal dihalogenation of allyl amides. E- and Z-alkenes with both aryl and alkyl substituents were compatible with this chemistry. This is the result of exquisite catalyst controlled regioselectivity enabling use of electronically unbiased substrates.
 

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