Gold‐Catalyzed [3 2]/Retro‐[3 2]/[3 2] Cycloaddition Cascade Reaction of N‐Alkoxyazomethine Ylides

Gold‐Catalyzed [3 2]/Retro‐[3 2]/[3 2] Cycloaddition Cascade Reaction of N‐Alkoxyazomethine Ylides: A novel cascade reaction has been developed for the synthesis of 2,6‐methanopyrrolo[1,2‐b]isoxazoles based on the gold‐catalyzed generation of an N‐allyloxyazomethine ylide. This reaction involves sequential...

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