Fulvene Synthesis by Rhodium(I)‐Catalyzed [2 2 1] Cycloaddition: Synthesis and Catalytic Activity of Tunable Cyclopentadienyl Rhodium(III) Complexes with Pendant Amides

Fulvene Synthesis by Rhodium(I)‐Catalyzed [2 2 1] Cycloaddition: Synthesis and Catalytic Activity of Tunable Cyclopentadienyl Rhodium(III) Complexes with Pendant Amides: It has been established that a RhI+/segphos complex catalyzes the [2+2+1] cycloaddition of 1,6‐diynes with cyclopropylideneacetamides to give substituted fulvenes in good yields. The reductive complexation...

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