First Stereoselective Total Synthesis of a Dimeric Naphthoquinonopyrano‐γ‐lactone: ( )‐γ‐Actinorhodin

First Stereoselective Total Synthesis of a Dimeric Naphthoquinonopyrano‐γ‐lactone: ( )‐γ‐Actinorhodin: We have accomplished the first total synthesis of an isomerically pure naphthoquinonopyrano‐γ‐lactone dimer, γ‐actinorhodin, in eleven steps. Two steps exploit pairs of peri‐MeO groups as unusual selectivity...

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