Direct Syn Addition of Two Silicon Atoms to a C≡C Triple Bond by Si−Si Bond Activation: Access to Reactive Disilylated Olefins

Direct Syn Addition of Two Silicon Atoms to a C≡C Triple Bond by Si−Si Bond Activation: Access to Reactive Disilylated Olefins: A catalytic intramolecular silapalladation of alkynes affords, in good yields and stereoselectively, syn‐disilylated heterocycles of different chemical structure and size. When applied to silylethers,...

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