An Agostic Iridium Pincer Complex as a Highly Efficient and Selective Catalyst for Monoisomerization of 1‐Alkenes to trans‐2‐Alkenes

An Agostic Iridium Pincer Complex as a Highly Efficient and Selective Catalyst for Monoisomerization of 1‐Alkenes to trans‐2‐Alkenes: A unique Ir complex (tBuNCCP)Ir with the pyridine–phosphine pincer as the sole ligand, featuring a dual agostic interaction between the Ir and two σ C−H bonds from a tBu substituent, has been prepared....

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