Regioselective Thiocarbonylation of Vinyl Arenes - Journal of the American Chemical Society (ACS Publications)

Regioselective Thiocarbonylation of Vinyl Arenes - Journal of the American Chemical Society (ACS Publications)
A palladium-catalyzed thiocarbonylation of styrene derivatives is reported for the first time. The combination of thiols as nucleophiles and a bidentate ligand ensures a unique reaction outcome with high regioselectivity toward the more valuable branched isomer and new reactivity.
 

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