Phosphoric Acid-Catalyzed Asymmetric Synthesis of SPINOL Derivatives - Journal of the American Chemical Society (ACS Publications)

Phosphoric Acid-Catalyzed Asymmetric Synthesis of SPINOL Derivatives - Journal of the American Chemical Society (ACS Publications)
Axially chiral 1,1′-spirobiindane-7,7′-diol (SPINOL) is the most fundamental and important privileged structure from which other chiral ligands containing a 1,1′-spirobiindane backbone are synthesized. Driven by the development of enantioselective syntheses of axially chiral SPINOL derivatives, we have successfully developed the first phosphoric acid-catalyzed asymmetric approach.
 

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