Efficient Synthesis of Trifluoromethyl Amines through a Formal Umpolung Strategy from the Bench‐Stable Precursor (Me4N)SCF3

Efficient Synthesis of Trifluoromethyl Amines through a Formal Umpolung Strategy from the Bench‐Stable Precursor (Me4N)SCF3: Reported herein is the one‐pot synthesis of trifluoromethylated amines at room temperature using the bench‐stable (Me4N)SCF3 reagent and AgF. The method is rapid, operationally simple and highly selective....

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