Azidoperfluoroalkanes: Synthesis and Application in Copper(I)‐Catalyzed Azide–Alkyne Cycloaddition

Azidoperfluoroalkanes: Synthesis and Application in Copper(I)‐Catalyzed Azide–Alkyne Cycloaddition: We report an efficient and scalable synthesis of azidotrifluoromethane (CF3N3) and longer perfluorocarbon‐chain analogues (RFN3; RF=C2F5, nC3F7, nC8F17), which enables the direct insertion of CF3 and perfluoroalkyl...

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