Cerium‐Catalyzed Hydrosilylation of Acrylates to Give α‐Silyl Esters

Cerium‐Catalyzed Hydrosilylation of Acrylates to Give α‐Silyl Esters: The homoleptic organocerium complex Ce{C(SiHMe2)3}3 (1) reacts with B(C6F5)3 to produce the zwitterionic bis(alkyl) hydridoborato Ce{C(SiHMe2)3}2HB(C6F5)3 (2). NMR and IR spectroscopy and X‐ray crystallography...

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