Mechanisms in Metal-Based Organic Chemistry 2

JOC: Mechanisms in Metal-Based Organic Chemistry





Mechanistic Insights into N—N Bond Cleavage in Catalytic Guanylation Reactions between 1,2-Diarylhydrazines and Carbodiimides
Ling Xu, Yu-Chen Wang, Wangyang Ma, Wen-Xiong Zhang, and Zhenfeng Xi


Pyridine-NHC: Effective Ligand in Pd-Catalyzed Cyclopropanation of Esters with Substituted Allyl Carbonates
Jian-Qiang Huang, Chang-Hua Ding, and Xue-Long Hou





Palladium(II)-Catalyzed Desulfitative Synthesis of Aryl Ketones from Sodium Arylsulfinates and Nitriles: Scope, Limitations, and Mechanistic Studies
Bobo Skillinghaug, Christian Sköld, Jonas Rydfjord, Fredrik Svensson, Malte Behrends, Jonas Sävmarker, Per J. R. Sjöberg, and Mats Larhed


Reaction Progress Kinetic Analysis of a Copper-Catalyzed Aerobic Oxidative Coupling Reaction with N-Phenyl Tetrahydroisoquinoline
Martin Scott, Abhishek Sud, Esther Boess, and Martin Klussmann

Kinetic and Computational Studies on Pd(I) Dimer-Mediated Halogen Exchange of Aryl Iodides
Indrek Kalvet, Karl J. Bonney, and Franziska Schoenebeck

 Mechanism and Selectivity of Methyl and Phenyl Migrations in Hypervalent Silylated Iminoquinones
Sukesh Shekar and Seth N. Brown


Decarboxylative-Coupling of Allyl Acetate Catalyzed by Group 10 Organometallics, [(phen)M(CH3)]+
Matthew Woolley, Alireza Ariafard, George N. Khairallah, Kim Hong-Yin Kwan, Paul S. Donnelly, Jonathan M. White, Allan J. Canty, Brian F. Yates, and Richard A. J. O’Hair

Dehydrative C–H/N–OH Functionalizations in H2O by Ruthenium(II) Catalysis: Subtle Effect of Carboxylate Ligands and Mechanistic Insight
Fanzhi Yang and Lutz Ackermann


Redox and Lewis Acid Relay Catalysis: A Titanocene/Zinc Catalytic Platform in the Development of Multicomponent Coupling Reactions
Joseph B. Gianino, Catherine A. Campos, Antonio J. Lepore, David M. Pinkerton, and Brandon L. Ashfeld


Palladium Complexes with Chelating Bis-NHC Ligands in the Mizoroki–Heck Reaction—Mechanism and Electronic Effects, a DFT Study
Christoph Allolio and Thomas Strassner

Ruthenium-Catalyzed Regioselective Allylic Trifluoromethylthiolation Reaction
Ke-Yin Ye, Xiao Zhang, Li-Xin Dai, and Shu-Li You

Exclusive Selectivity in the One-Pot Formation of C–C and C–Se Bonds Involving Ni-Catalyzed Alkyne Hydroselenation: Optimization of the Synthetic Procedure and a Mechanistic Study
Nikolay V. Orlov, Igor V. Chistyakov, Levon L. Khemchyan, Valentine P. Ananikov, Irina P. Beletskaya, and Zoya A. Starikova


Formation of Three New Bonds and Two Stereocenters in Acyclic Systems by Zinc-Mediated Enantioselective Alkynylation of Acylsilanes, Brook Rearrangement, and Ene-Allene Carbocyclization Reactions
Polina Smirnov, Einat Katan, Jomon Mathew, Arseni Kostenko, Miriam Karni, Anne Nijs, Carsten Bolm, Yitzhak Apeloig, and Ilan Marek



Origin of Inversion versus Retention in the Oxidative Addition of 3-Chloro-cyclopentene to Pd(0)Ln
Larry M. Wolf and Walter Thiel

Homologation of Boronic Esters with Organolithium Compounds: A Computational Assessment of Mechanism
Stéphanie Essafi, Simone Tomasi, Varinder K. Aggarwal, and Jeremy N. Harvey


Metal–Ligand Binding Interactions in Rhodium/Palladium-Catalyzed Synthesis of Dihydroquinolines
Lei Zhang, Jane Panteleev, and Mark Lautens

Mechanism, Reactivity, and Selectivity of Nickel-Catalyzed [4 + 4 + 2] Cycloadditions of Dienes and Alkynes
Xin Hong, Dane Holte, Daniel C. G. Götz, Phil S. Baran, and K. N. Houk

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