Mechanisms in Metal-Based Organic Chemistry 1

JOC:  Mechanisms in Metal-Based Organic Chemistry

 Palladium-Catalyzed Thiocarbonylation of Aryl, Vinyl, and Benzyl Bromides
Mia N. Burhardt, Andreas Ahlburg, and Troels Skrydstrup


Investigating the Nature of Palladium Chain-Walking in the Enantioselective Redox-Relay Heck Reaction of Alkenyl Alcohols
Margaret J. Hilton, Li-Ping Xu, Per-Ola Norrby, Yun-Dong Wu, Olaf Wiest, and Matthew S. Sigman







Carbonylation of cis-Disubstituted Epoxides to trans-β-Lactones: Catalysts Displaying Steric and Contrasteric Regioselectivity
Michael Mulzer and Geoffrey W. Coates

Synthesis of Indolo[2,1-a]isoquinolines via a Triazene-Directed C–H Annulation Cascade
Huan Sun, Chengming Wang, Yun-Fang Yang, Ping Chen, Yun-Dong Wu, Xinhao Zhang, and Yong Huang



Medium-Sized Heterocycle Synthesis by the Use of Synergistic Effects of Ni-NHC and γ-Coordination in Cycloisomerization
Chun-Yu Ho and Lisi He


Lithium Diisopropylamide-Mediated Lithiation of 1,4-Difluorobenzene under Nonequilibrium Conditions: Role of Monomer-, Dimer-, and Tetramer-Based Intermediates and Lessons about Rate Limitation
Jun Liang, Alexander C. Hoepker, Angela M. Bruneau, Yun Ma, Lekha Gupta, and David B. Collum


Mechanistic Study of the Selectivity of Olefin versus Cyclobutene Formation by Palladium(0)-Catalyzed Intramolecular C(sp3)–H Activation
Christos E. Kefalidis, Michaël Davi, Philipp M. Holstein, Eric Clot, and Olivier Baudoin


Mechanisms and Reactivity Differences for Cycloaddition of Anhydride to Alkyne Catalyzed by Palladium and Nickel Catalysts: Insight from Density Functional Calculations
Hujun Xie, Qiang Sun, Gerui Ren, and Zexing Cao


Nickel(II)-Catalyzed Direct Arylation of C–H Bonds in Aromatic Amides Containing an 8-Aminoquinoline Moiety as a Directing Group
Ayana Yokota, Yoshinori Aihara, and Naoto Chatani




Direct Arylation of C(sp3)–H Bonds in Aliphatic Amides with Diaryliodonium Salts in the Presence of a Nickel Catalyst
Miki Iyanaga, Yoshinori Aihara, and Naoto Chatani


Factors Controlling Selectivity in the Ring-Opening Metathesis Polymerization of 3-Substituted Cyclooctenes by Monoaryloxide Pyrrolide Imido Alkylidene (MAP) Catalysts
Henry Martinez, Marc A. Hillmyer, and Christopher J. Cramer

DFT Study of the Mechanism and Stereochemistry of the Rh(I)-Catalyzed Diels–Alder Reactions between Electronically Neutral Dienes and Dienophiles
Wei Liao and Zhi-Xiang Yu

Role of the Base in Buchwald–Hartwig Amination
Ylva Sunesson, Elaine Limé, Sten O. Nilsson Lill, Rebecca E. Meadows, and Per-Ola Norrby


Theoretical Studies on the Regioselectivity of Iridium-Catalyzed 1,3-Dipolar Azide–Alkyne Cycloaddition Reactions
Qiong Luo, Guochen Jia, Jianwei Sun, and Zhenyang Lin




Computational Characterization of the Mechanism for Coinage-Metal-Catalyzed Carboxylation of Terminal Alkynes
Jesús Jover and Feliu Maseras



Mechanism of SmI2/Amine/H2O-Promoted Chemoselective Reductions of Carboxylic Acid Derivatives (Esters, Acids, and Amides) to Alcohols
Michal Szostak, Malcolm Spain, Andrew J. Eberhart, and David J. Procter 

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