Total Syntheses and/of natural products

Angewchem


Light-Mediated Total Synthesis of 17-Deoxyprovidencin
Dr. Nina Toelle, Dr. Harald Weinstabl, Dr. Tanja Gaich and Prof. Dr. Johann Mulzer


Total Synthesis of (±)-Clavilactones A, B, and Proposed D through Iron-Catalyzed Carbonylation–Peroxidation of Olefin
Leiyang Lv, Prof. Dr. Baojian Shen and Prof. Dr. Zhiping Li


A Convergent Total Synthesis of the Telomerase Inhibitor (±)-γ-Rubromycin
Dr. Michael Wilsdorf and Prof. Dr. Hans-Ulrich Reissig

 Catalysis-Based Total Synthesis of Putative Mandelalide A
Dipl.-Chem. Jens Willwacher and Prof. Alois Fürstner


Total Synthesis of the Antibiotic Kendomycin: A Macrocyclization Using the Tsuji–Trost Etherification
Dr. Tetsuya Sengoku, Dr. Shu Xu, Kenji Ogura, Yoshinori Emori, Kenji Kitada, Prof. Dr. Daisuke Uemura and Prof. Dr. Hirokazu Arimoto

 Short Chemoenzymatic Total Synthesis of ent-Hydromorphone: An Oxidative Dearomatization/Intramolecular [4+2] Cycloaddition/Amination Sequence
Vimal Varghese and Prof. Tomas Hudlicky


Short Stereoselective Synthesis of the Phytophthora Universal Mating Hormone α1 Using Lithiation/Borylation Reactions
Dr. Alexander P. Pulis, Dr. Philipp Fackler and Prof. Varinder K. Aggarwal


Jacs



Total Synthesis of Halichondrin A, the Missing Member in the Halichondrin Class of Natural Products
Atsushi Ueda, Akihiko Yamamoto, Daisuke Kato, and Yoshito Kishi


Two-Phase Synthesis of (−)-Taxuyunnanine D
Nathan C. Wilde, Minetaka Isomura, Abraham Mendoza, and Phil S. Baran


Total Synthesis of the Akuammiline Alkaloid Picrinine
Joel M. Smith, Jesus Moreno, Ben W. Boal, and Neil K. Garg

JOC

 Catalytic Asymmetric Claisen Rearrangement of Gosteli-Type Allyl Vinyl Ethers: Total Synthesis of (−)-9,10-Dihydroecklonialactone B
Julia Becker, Lena Butt, Valeska von Kiedrowski, Elisabeth Mischler, Florian Quentin, and Martin Hiersemann

Ligand-Controlled C(sp3)–H Arylation and Olefination in Synthesis of Unnatural Chiral α–Amino Acids

Science

Ligand-Controlled C(sp3)–H Arylation and Olefination in Synthesis of Unnatural Chiral α–Amino Acids
Jian He, Suhua Li, Youqian Deng, Haiyan Fu, Brian N. Laforteza, Jillian E. Spangler, Anna Homs, and Jin-Quan Yu

Regioselective Hydration of Terminal Halo-Substituted Propargyl Carboxylates by Gold Catalyst: Synthesis of α-Acyloxy α′-Halo Ketones

Synthesis of Chiral α-Diarylacetic Esters by Stereospecific 1,2-Aryl Migration Promoted by in Situ Generated Acetals from Benzoins

Synthesis of Naphthalene Derivatives from ortho-Alkynylacetophenone Derivatives via Tandem in Situ Incorporation of Acetal and Intramolecular Heteroalkyne Metathesis/Annulation

Orthogonal Reactivity of Acyl Azides in C–H Activation: Dichotomy between C–C and C–N Amidations Based on Catalyst Systems

Rh(III)- and Ir(III)-Catalyzed C–H Alkynylation of Arenes under Chelation Assistance

An Isothiourea-Catalyzed Asymmetric [2,3]-Rearrangement of Allylic Ammonium Ylides

Jacs

An Isothiourea-Catalyzed Asymmetric [2,3]-Rearrangement of Allylic Ammonium Ylides
Thomas H. West, David S. B. Daniels, Alexandra M. Z. Slawin, and Andrew D. Smith

Alkoxyboration: Ring-Closing Addition of B–O σ Bonds across Alkynes

Jacs

Alkoxyboration: Ring-Closing Addition of B–O σ Bonds across Alkynes
Joshua J. Hirner, Darius J. Faizi, and Suzanne A. Blum

An Efficient Approach toward the Synthesis of Planar Chiral Metallocene Compounds

Direct C–N Coupling of Imidazoles with Aromatic and Benzylic Compounds via Electrooxidative C–H Functionalization

Ligand-Controlled Asymmetric Arylation of Aliphatic α-Amino Anion Equivalents

Hexafluoroantimonic Acid Catalysis: Formal [3+2+2] Cycloaddition of Aziridines with Two Alkynes

Angewchem

Hexafluoroantimonic Acid Catalysis: Formal [3+2+2] Cycloaddition of Aziridines with Two Alkynes
Ming-Bo Zhou, Ren-Jie Song and Prof. Dr. Jin-Heng Li

Oxidative Cross-Coupling of Allenyl Ketones and Organoboronic Acids: Expeditious Synthesis of Highly Substituted Furans

Angewchem

Oxidative Cross-Coupling of Allenyl Ketones and Organoboronic Acids: Expeditious Synthesis of Highly Substituted Furans
Ying Xia, Dr. Yamu Xia, Rui Ge, Zhen Liu, Dr. Qing Xiao, Dr. Yan Zhang and Prof. Dr. Jianbo Wang

The Isolation and Characterization of a Rhodacycle Intermediate Implicated in Metal-Catalyzed Reactions of Alkylidenecyclopropanes

Angewchem

The Isolation and Characterization of a Rhodacycle Intermediate Implicated in Metal-Catalyzed Reactions of Alkylidenecyclopropanes
Dr. Phillip A. Inglesby, Dr. John Bacsa, Daniela E. Negru and Prof. P. Andrew Evans

Merging Aerobic Oxidation and Enamine Catalysis in the Asymmetric α-Amination of β-Ketocarbonyls Using N-Hydroxycarbamates as Nitrogen Sources

Enantioselective Synthesis of Allylboronates and Allylic Alcohols by Copper-Catalyzed 1,6-Boration

Angewchem

Enantioselective Synthesis of Allylboronates and Allylic Alcohols by Copper-Catalyzed 1,6-Boration
Dr. Yunfei Luo, Iain D. Roy, Amaël G. E. Madec and Prof. Hon Wai Lam

Rhodium(III)-Catalyzed Alkenylation Reactions of 8-Methylquinolines with Alkynes by C(sp3)[BOND]H Activation

Angewchem

Rhodium(III)-Catalyzed Alkenylation Reactions of 8-Methylquinolines with Alkynes by C(sp3)[BOND]H Activation
Bingxian Liu, Tao Zhou, Prof. Dr. Bin Li, Prof. Shansheng Xu, Prof. Dr. Haibin Song and Prof. Dr. Baiquan Wang

Metal-Triflate-Catalyzed Synthesis of Polycyclic Tertiary Alcohols by Cyclization of γ-Allenic Ketones

A Simple 3,4-Ethylenedioxythiophene Based Hole-Transporting Material for Perovskite Solar Cells

Angewchem

A Simple 3,4-Ethylenedioxythiophene Based Hole-Transporting Material for Perovskite Solar Cells
Dr. Hairong Li, Kunwu Fu, Prof. Anders Hagfeldt, Prof. Michael Grätzel, Prof. Subodh G. Mhaisalkar and Prof. Andrew C. Grimsdale

Reductive Amination without an External Hydrogen Source

Angewchem

Reductive Amination without an External Hydrogen Source
Dr. Denis Chusov and Prof. Benjamin List

Diastereoselective Carbocyclization of 1,6-Heptadienes Triggered by Rhodium-Catalyzed Activation of an Olefinic C-H Bond

Angewchem

Diastereoselective Carbocyclization of 1,6-Heptadienes Triggered by Rhodium-Catalyzed Activation of an Olefinic C-H Bond
Dr. Christophe Aïssa, Kelvin Y. T. Ho, Dr. Daniel J. Tetlow and María Pin-Nó

Metal- and Reagent-Free Highly Selective Anodic Cross-Coupling Reaction of Phenols

Angewchem

Metal- and Reagent-Free Highly Selective Anodic Cross-Coupling Reaction of Phenols
Bernd Elsler, Dr. Dieter Schollmeyer, Dr. Katrin Marie Dyballa, Prof. Dr. Robert Franke and Prof. Dr. Siegfried R. Waldvogel

Synthesis of 7,8-Dehydropurpurin Dimers and Their Conversion into Conformationally Constrained β-to-β Vinylene-Bridged Porphyrin Dimers

Angewchem

Synthesis of 7,8-Dehydropurpurin Dimers and Their Conversion into Conformationally Constrained β-to-β Vinylene-Bridged Porphyrin Dimers
Norihito Fukui, Prof. Dr. Hideki Yorimitsu, Dr. Jong Min Lim, Prof. Dr. Dongho Kim and Prof. Dr. Atsuhiro Osuka

Amide Synthesis by Nucleophilic Attack of Vinyl Azides

Angewchem

Amide Synthesis by Nucleophilic Attack of Vinyl Azides
Feng-Lian Zhang, Dr. Yi-Feng Wang, Geoffroy Hervé Lonca, Xu Zhu and Prof. Shunsuke Chiba

cis-Specific Hydrofluorination of Alkenylarenes under Palladium Catalysis through an Ionic Pathway

Angewchem

cis-Specific Hydrofluorination of Alkenylarenes under Palladium Catalysis through an Ionic Pathway
Dr. Enrico Emer, Lukas Pfeifer, Dr. John M. Brown and Prof. Véronique Gouverneur

Stereoselective Metal-Free Synthesis of β-Amino Thioesters with Tertiary and Quaternary Stereogenic Centers

Angewchem

Stereoselective Metal-Free Synthesis of β-Amino Thioesters with Tertiary and Quaternary Stereogenic Centers
Dr. Annette Bahlinger, Dr. Sven P. Fritz and Prof. Helma Wennemers

Stereoselective Silylcupration of Conjugated Alkynes in Water at Room Temperature

Angewchem

Stereoselective Silylcupration of Conjugated Alkynes in Water at Room Temperature
Roscoe T. H. Linstadt, Carl A. Peterson, Daniel J. Lippincott, Carina I. Jette and Prof. Bruce H. Lipshutz

A Chiral Thioxanthone as an Organocatalyst for Enantioselective [2+2] Photocycloaddition Reactions Induced by Visible Light

Regio- and Stereoselective 1,2-Dihydropyridine Alkylation/Addition Sequence for the Synthesis of Piperidines with Quaternary Centers

Angewchem

Regio- and Stereoselective 1,2-Dihydropyridine Alkylation/Addition Sequence for the Synthesis of Piperidines with Quaternary Centers
Simon Duttwyler, Shuming Chen, Colin Lu, Brandon Q. Mercado, Prof. Dr. Robert G. Bergman and Prof. Dr. Jonathan A. Ellman

Dual Platinum and Pyrrolidine Catalysis in the Direct Alkylation of Allylic Alcohols: Selective Synthesis of Monoallylation Products

Angewchem

Dual Platinum and Pyrrolidine Catalysis in the Direct Alkylation of Allylic Alcohols: Selective Synthesis of Monoallylation Products
Ryozo Shibuya, Lu Lin, Yasuhito Nakahara, Prof. Dr. Kazushi Mashima and Prof. Dr. Takashi Ohshima

Rhodium-Catalyzed Intermolecular C–H Silylation of Arenes with High Steric Regiocontrol

Copper-catalyzed alkene diamination: synthesis of chiral 2-aminomethyl indolines and pyrrolidines

Iron-catalyzed carbonylative Suzuki reactions under atmospheric pressure of carbon monoxide

Nickel-catalyzed chelation-assisted direct arylation of unactivated C(sp3)–H bonds with aryl halides

ChemComm
Nickel-catalyzed chelation-assisted direct arylation of unactivated C(sp3)–H bonds with aryl halides Mingliang Li, Jiaxing Dong, Xiaolei Huang, Kaizhi Li, Qian Wu, Feijie Song and Jingsong You 

Applications of C–H Functionalization Logic to Cyclobutane Synthesis

Boron Trifluoride Etherate Functioning as a Fluorine Source in an Iodosobenzene-Mediated Intramolecular Aminofluorination of Homoallylic Amines

C–H Activation of Methyl Arenes in the MnO2-Mediated Aroylation of N-Chlorosulfoximines

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