Direct Stereospecific Synthesis of Unprotected N-H and N-Me Aziridines from Olefins

Science
Direct Stereospecific Synthesis of Unprotected N-H and N-Me Aziridines from Olefins
Jawahar L. Jat, Mahesh P. Paudyal, Hongyin Gao, Qing-Long Xu, Muhammed Yousufuddin, Deepa Devarajan, Daniel H. Ess, László Kürti, and John R. Falck

Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Alkyl Grignard Reagents and Identification of Selective Anti-Breast-Cancer Agents

Angewchem
Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Alkyl Grignard Reagents and Identification of Selective Anti-Breast-Cancer Agents
Ivelina M. Yonova, A. George Johnson, Charlotte A. Osborne, Dr. Curtis E. Moore, Prof. Naomi S. Morrissette and Prof. Elizabeth R. Jarvo

Radical Cyclization/ipso-1,4-Aryl Migration Cascade: Asymmetric Synthesis of 3,3-Difluoro-2-propanoylbicyclo[3.3.0]octanes

Angewchem
Radical Cyclization/ipso-1,4-Aryl Migration Cascade: Asymmetric Synthesis of 3,3-Difluoro-2-propanoylbicyclo[3.3.0]octanes
Watcharaporn Thaharn, Dr. Darunee Soorukram, Dr. Chutima Kuhakarn, Dr. Patoomratana Tuchinda, Prof. Dr. Vichai Reutrakul and Prof. Dr. Manat Pohmakotr

Rhodium(II)-Catalyzed Nondirected Oxidative Alkenylation of Arenes: Arene Loading at One Equivalent

Angewchem
Rhodium(II)-Catalyzed Nondirected Oxidative Alkenylation of Arenes: Arene Loading at One Equivalent
Dr. Harit U. Vora, Anthony P. Silvestri, Casper J. Engelin and Prof. Dr. Jin-Quan Yu

Rapid Synthesis of Fused N-Heterocycles by Transition-Metal-Free Electrophilic Amination of Arene C[BOND]H Bonds

Angewchem
Rapid Synthesis of Fused N-Heterocycles by Transition-Metal-Free Electrophilic Amination of Arene C-H Bonds
Dr. Hongyin Gao, Dr. Qing-Long Xu, Dr. Muhammed Yousufuddin, Prof. Daniel H. Ess and Prof. László Kürti

Palladium-Catalyzed Oxidative Carbonylation of N-Allylamines for the Synthesis of β-Lactams

Angewchem
Palladium-Catalyzed Oxidative Carbonylation of N-Allylamines for the Synthesis of β-Lactams
Wu Li, Dr. Chao Liu, Prof. Heng Zhang, Keyin Ye, Guanghui Zhang, Wangzheng Zhang, Zhengli Duan, Prof. Shuli You and Prof. Aiwen Lei

A Multicomponent Ni-, Zr-, and Cu-Catalyzed Strategy for Enantioselective Synthesis of Alkenyl-Substituted Quaternary Carbons

Collective Synthesis of Cladiellins Based on the Gold-Catalyzed Cascade Reaction of 1,7-Diynes

Angewchem

Collective Synthesis of Cladiellins Based on the Gold-Catalyzed Cascade Reaction of 1,7-Diynes
Guozong Yue, Yun Zhang, Lichao Fang, Prof. Dr. Chuang-chuang Li, Prof. Dr. Tuoping Luo and Prof. Dr. Zhen Yang

Broadly Applicable Z- and Diastereoselective Ring-Opening/Cross-Metathesis Catalyzed by a Dithiolate Ru Complex

Angewchem
Broadly Applicable Z- and Diastereoselective Ring-Opening/Cross-Metathesis Catalyzed by a Dithiolate Ru Complex
Ming Joo Koh, R. Kashif M. Khan, Dr. Sebastian Torker and Prof. Amir H. Hoveyda

Copper-Catalyzed α-Amination of Phosphonates and Phosphine Oxides: A Direct Approach to α-Amino Phosphonic Acids and Derivatives

Iridium-Catalyzed Intermolecular Azide–Alkyne Cycloaddition of Internal Thioalkynes under Mild Conditions

Turning Regioselectivity into Stereoselectivity: Efficient Dual Resolution of P-Stereogenic Phosphine Oxides through Bifurcation of the Reaction Pathway of a Common Intermediate

Metal-Free Aminosulfonylation of Aryldiazonium Tetrafluoroborates with DABCO⋅(SO2)2 and Hydrazines

Angewchem
Metal-Free Aminosulfonylation of Aryldiazonium Tetrafluoroborates with DABCO⋅(SO2)2 and Hydrazines
Danqing Zheng, Yuanyuan An, Dr. Zhenhua Li and Prof. Dr. Jie Wu

Substrate-Directed Hydroacylation: Rhodium-Catalyzed Coupling of Vinylphenols and Nonchelating Aldehydes

Powerful Fluoroalkoxy Molybdenum(V) Reagent for Selective Oxidative Arene Coupling Reaction

Angewchem
Powerful Fluoroalkoxy Molybdenum(V) Reagent for Selective Oxidative Arene Coupling Reaction
Moritz Schubert, Jana Leppin, Dr. Kathrin Wehming, Dr. Dieter Schollmeyer, Prof. Dr. Katja Heinze and Prof. Dr. Siegfried R. Waldvogel

A Regio- and Stereoselective ω-Transaminase/Monoamine Oxidase Cascade for the Synthesis of Chiral 2,5-Disubstituted Pyrrolidines

Angewchem
A Regio- and Stereoselective ω-Transaminase/Monoamine Oxidase Cascade for the Synthesis of Chiral 2,5-Disubstituted Pyrrolidines
Dr. Elaine O'Reilly, Cesar Iglesias, Dr. Diego Ghislieri, Dr. Jennifer Hopwood, Dr. James L. Galman, Dr. Richard C. Lloyd and Prof. Nicholas J. Turner

An Enantioselective Inverse-Electron-Demand Imino Diels–Alder Reaction

Angewchem

An Enantioselective Inverse-Electron-Demand Imino Diels–Alder Reaction
M. Sc. Vincent Eschenbrenner-Lux, Dipl.-Biol. Philipp Küchler, Dr. Slava Ziegler, Dr. Kamal Kumar and Prof. Herbert Waldmann

Iridium-Catalyzed Direct C-H Amidation with Weakly Coordinating Carbonyl Directing Groups under Mild Conditions

Hydrogenative Dearomatization of Pyridine and Asymmetric Aza-Friedel–Crafts Alkylation Sequence

Near-IR Absorbing Nickel(II) Porphyrinoids Prepared by Regioselective Insertion of Silylenes into Antiaromatic Nickel(II) Norcorrole

Angewchem

Near-IR Absorbing Nickel(II) Porphyrinoids Prepared by Regioselective Insertion of Silylenes into Antiaromatic Nickel(II) Norcorrole
Takaki Fukuoka, Kenya Uchida, Dr. Young Mo Sung, Prof. Dr. Ji-Young Shin, Prof. Dr. Shintaro Ishida, Dr. Jong Min Lim, Prof. Dr. Satoru Hiroto, Prof. Dr. Ko Furukawa, Prof. Dr. Dongho Kim, Prof. Dr. Takeaki Iwamoto and Prof. Dr. Hiroshi Shinokubo

Pd/C as a Catalyst for Completely Regioselective C-H Functionalization of Thiophenes under Mild Conditions

Angewchem

Pd/C as a Catalyst for Completely Regioselective C-H Functionalization of Thiophenes under Mild Conditions
Dan-Tam D. Tang, Dr. Karl D. Collins, Johannes B. Ernst and Prof. Dr. Frank Glorius

A Photochemical Strategy for Lignin Degradation at Room Temperature

Jacs
A Photochemical Strategy for Lignin Degradation at Room Temperature
John D. Nguyen, Bryan S. Matsuura, and Corey R. J. Stephenson

Site-Differentiated Polyboron Arenes Prepared by Direct C-H Borylation and Their Highly Selective Suzuki–Miyaura Cross-Coupling Reactions

S-((Phenylsulfonyl)difluoromethyl)thiophenium Salts: Carbon-Selective Electrophilic Difluoromethylation of β-Ketoesters, β-Diketones, and Dicyanoalkylidenes

Angewchem
S-((Phenylsulfonyl)difluoromethyl)thiophenium Salts: Carbon-Selective Electrophilic Difluoromethylation of β-Ketoesters, β-Diketones, and Dicyanoalkylidenes
Xin Wang, Guokai Liu, Dr. Xiu-Hua Xu, Naoyuki Shibata, Etsuko Tokunaga and Prof. Dr. Norio Shibata

Divergent Syntheses of Fused β-Naphthol and Indene Scaffolds by Rhodium-Catalyzed Direct and Decarbonylative Alkyne–Benzocyclobutenone Couplings

Palladium-Catalyzed Difluoroalkylation of Aryl Boronic Acids: A New Method for the Synthesis of Aryldifluoromethylated Phosphonates and Carboxylic Acid Derivatives

Ruthenium-Catalyzed Cascade C-H Functionalization of Phenylacetophenones

Angewchem

Ruthenium-Catalyzed Cascade C-H Functionalization of Phenylacetophenones
Dr. Vaibhav P. Mehta, Dr. José-Antonio García-López and Prof. Michael F. Greaney

Chemoselective Catalytic Conjugate Addition of Alcohols over Amines

Angewchem

Chemoselective Catalytic Conjugate Addition of Alcohols over Amines
Shuhei Uesugi, Zhao Li, Dr. Ryo Yazaki and Prof. Dr. Takashi Ohshima

Ascorbic Acid as an Initiator for the Direct C-H Arylation of (Hetero)arenes with Anilines Nitrosated In Situ

Angewchem


Ascorbic Acid as an Initiator for the Direct C-H Arylation of (Hetero)arenes with Anilines Nitrosated In Situ
Dr. Fernando Pinacho Crisóstomo, Dr. Tomás Martín and Dr. Romen Carrillo

Iron(II)-Catalyzed Direct Cyanation of Arenes with Aryl(cyano)iodonium Triflates

Jacs

Iron(II)-Catalyzed Direct Cyanation of Arenes with Aryl(cyano)iodonium Triflates
Zhibin Shu, Wenzhi Ji, Xi Wang, Yujing Zhou, Prof. Dr. Yan Zhang and Prof. Dr. Jianbo Wang

Total Synthesis of (±)-Aspidophylline A

Jacs


Total Synthesis of (±)-Aspidophylline A
Dr. Weiwu Ren, Dr. Qian Wang and Prof. Dr. Jieping Zhu

A General Catalytic Hydroamidation of 1,3-Dienes: Atom-Efficient Synthesis of N-Allyl Heterocycles, Amides, and Sulfonamides

Formation of a Room Temperature Stable FeV(O) Complex: Reactivity Toward Unactivated C–H Bonds

Jacs

Formation of a Room Temperature Stable FeV(O) Complex: Reactivity Toward Unactivated C–H Bonds
Munmun Ghosh, Kundan K. Singh, Chakadola Panda, Andrew Weitz, Michael P. Hendrich, Terrence J. Collins, Basab B. Dhar, and Sayam Sen Gupta

Nickel-Catalyzed Site-Selective Alkylation of Unactivated C(sp3)–H Bonds

Photoinduced, Copper-Catalyzed Alkylation of Amides with Unactivated Secondary Alkyl Halides at Room Temperature

Jacs



Photoinduced, Copper-Catalyzed Alkylation of Amides with Unactivated Secondary Alkyl Halides at Room Temperature
Hien-Quang Do, Shoshana Bachman, Alex C. Bissember, Jonas C. Peters, and Gregory C. Fu

Mechanism, Reactivity, and Selectivity in Palladium-Catalyzed Redox-Relay Heck Arylations of Alkenyl Alcohols

Jacs

Mechanism, Reactivity, and Selectivity in Palladium-Catalyzed Redox-Relay Heck Arylations of Alkenyl Alcohols
Liping Xu, Margaret J. Hilton, Xinhao Zhang, Per-Ola Norrby, Yun-Dong Wu, Matthew S. Sigman, and Olaf Wiest

Activation of Aryl Halides at Gold(I): Practical Synthesis of (P,C) Cyclometalated Gold(III) Complexes

Jacs
Activation of Aryl Halides at Gold(I): Practical Synthesis of (P,C) Cyclometalated Gold(III) Complexes
Johannes Guenther, Sonia Mallet-Ladeira, Laura Estevez, Karinne Miqueu, Abderrahmane Amgoune, and Didier Bourissou

Pd-Catalyzed Intramolecular Aminohydroxylation of Alkenes with Hydrogen Peroxide as Oxidant and Water as Nucleophile

Mechanisms and Origins of Switchable Chemoselectivity of Ni-Catalyzed C(aryl)–O and C(acyl)–O Activation of Aryl Esters with Phosphine Ligands

A Broadly Applicable NHC–Cu-Catalyzed Approach for Efficient, Site-, and Enantioselective Coupling of Readily Accessible (Pinacolato)alkenylboron Compounds to Allylic Phosphates and Applications to Natural Product Synthesis

Intramolecular Dearomatizing [3 + 2] Annulation of α-Imino Carbenoids with Aryl Rings Furnishing 3,4-Fused Indole Skeletons

Synthesis and Characterization of [5]Cycloparaphenylene



Jacs



Synthesis and Characterization of [5]Cycloparaphenylene
Eiichi Kayahara, Vijay Kumar Patel, and Shigeru Yamago

Metal-Catalyzed [6 + 3] Cycloaddition of Tropone with Azomethine Ylides: A Practical Access to Piperidine-Fused Bicyclic Heterocycles

Jacs
Metal-Catalyzed [6 + 3] Cycloaddition of Tropone with Azomethine Ylides: A Practical Access to Piperidine-Fused Bicyclic Heterocycles
Honglei Liu, Yang Wu, Yan Zhao, Zhen Li, Lei Zhang, Wenjun Yang, Hui Jiang, Chengfeng Jing, Hao Yu, Bo Wang, Yumei Xiao, and Hongchao Guo

Copper-Catalyzed Intermolecular Amidation and Imidation of Unactivated Alkanes

Jacs

Copper-Catalyzed Intermolecular Amidation and Imidation of Unactivated Alkanes
Ba L. Tran, Bijie Li, Matthias Driess, and John F. Hartwig

Highly Coplanar Very Long Oligo(alkylfuran)s: A Conjugated System with Specific Head-To-Head Defect


Jacs



Highly Coplanar Very Long Oligo(alkylfuran)s: A Conjugated System with Specific Head-To-Head Defect
Xu-Hui Jin, Dennis Sheberla, Linda J. W. Shimon, and Michael Bendikov

Air-Stable Gold Nanoparticles Ligated by Secondary Phosphine Oxides for the Chemoselective Hydrogenation of Aldehydes: Crucial Role of the Ligand

Mechanistic Studies of the Rhodium-Catalyzed Direct C–H Amination Reaction Using Azides as the Nitrogen Source

Jacs



Mechanistic Studies of the Rhodium-Catalyzed Direct C–H Amination Reaction Using Azides as the Nitrogen Source
Sae Hume Park, Jaesung Kwak, Kwangmin Shin, Jaeyune Ryu, Yoonsu Park, and Sukbok Chang

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