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Gold–Gold Cooperation in the Addition of Methanol to Alkynes


Angewchem

Prof. Jana Roithová, Dr. Štěpánka Janková, Lucie Jašíková, Dr. Jiří Váňa and Dr. Simona Hybelbauerová

Catalytic Asymmetric [4+2] Annulation Initiated by an Aza-Rauhut–Currier Reaction

Total Synthesis of (±)-Decinine

OL

Total Synthesis of (±)-Decinine via an Oxidative Biaryl Coupling with Defined Axial Chirality
Zhen-Hua Shan, Ji Liu, Ling-Min Xu, Ye-Feng Tang, Jia-Hua Chen, and Zhen Yang

Metal/Brønsted Acid Relay Catalysis for the Intramolecular Double Hydroarylation

Electronic Effect Directed Au(I)-Catalyzed Cyclic C2–H Bond Functionalization

Gold(I)-Catalyzed Asymmetric Cyclopropenation of Internal Alkynes

Highly regio-, diastereo- and enantioselective one-pot gold/chiral Brønsted acid-catalysed cascade synthesis

Nature: News In Focus :Open Access

Nature: News In Focus


Being the first to try something new is nerve-wracking — so it is always a relief to see someone else follow your lead. When the UK government announced on 16 July that it would require much of the country’s taxpayer-funded research to be open-access from April 2013, it was not immediately clear whether the move would set a trend or prove to be an isolated gamble — one that would leave the United Kingdom essentially giving away its research for free while still paying to read everyone else’s.

To read more go to this link.

Oxidative Heck Reactions using Aryltrifluoroborates

ChemOpen

Oxidative Heck Reactions using Aryltrifluoroborates and Aryl N-Methyliminodiacetic Acid (MIDA) Boronates 
Dr. Jonas Sävmarker, Dr. Jonas Lindh, Dr. Peter Nilsson, Dr. Per J. R. Sjöberg and Prof. Mats Larhed

Expeditous Route to Eight-Membered Heterocycles By Nickel-Catalyzed Cycloaddition

Catalytic Asymmetric Conjugate Addition of Thiols to α,β-Unsaturated Thioamides

Alkynoate Synthesis through the Vinylogous Reactivity of Rhodium(II) Carbenoids

Angewchem

Alkynoate Synthesis through the Vinylogous Reactivity of Rhodium(II) Carbenoids
Dr. Damien Valette, Dr. Yajing Lian, John P. Haydek, Dr. Kenneth I. Hardcastle and Prof. Dr. Huw M. L. Davies

Triflic Anhydride Activated Reductive Alkylation

Mild Metal-Free Tandem α-Alkylation/Cyclization of N-Benzyl Carbamates

Angewchem

Mild Metal-Free Tandem α-Alkylation/Cyclization of N-Benzyl Carbamates with Simple Olefins
Dr. Heinrich Richter, Dr. Roland Fröhlich, Dr. Constantin-Gabriel Daniliuc and Dr. Olga García Mancheño

Nucleophilic Allylation of Cyclic Imines with Allylboron Reagents

Angewchem

Enantioselective Rhodium-Catalyzed Nucleophilic Allylation of Cyclic Imines with Allylboron Reagents
Dr. Yunfei Luo, Hamish B. Hepburn, Nawasit Chotsaeng and Dr. Hon Wai Lam

Chemoselective N-Acylation of Indoles and Oxazolidinones with Carbonylazoles

Angewchem

Chemoselective N-Acylation of Indoles and Oxazolidinones with Carbonylazoles
Stephen T. Heller, Erica E. Schultz and Prof. Richmond Sarpong

Enantioselective Iridium-Catalyzed Hydrogenation of 3,4-Disubstituted Isoquinolines

Angewchem

Enantioselective Iridium-Catalyzed Hydrogenation of 3,4-Disubstituted Isoquinolines
Dr. Lei Shi, Zhi-Shi Ye, Liang-Liang Cao, Ran-Ning Guo, Yue Hu and Prof. Yong-Gui Zhou

Gold–Gold Cooperation in the Addition of Methanol to Alkynes

Angewchem

Gold–Gold Cooperation in the Addition of Methanol to Alkynes
Prof. Jana Roithová, Dr. Štěpánka Janková, Lucie Jašíková, Dr. Jiří Váňa and Dr. Simona Hybelbauerová

Aerobic Dehydrogenative Cyclization of N-Methyl-N-phenylhydrazones

Angewchem

Copper-Catalyzed Aerobic Dehydrogenative Cyclization of N-Methyl-N-phenylhydrazones: Synthesis of Cinnolines
Dr. Guangwu Zhang, Jinmin Miao, Yan Zhao and Prof. Dr. Haibo Ge

Cross-Dehydrogenative Coupling of Furan and Thiophene Derivatives

Angewchem

Selective Rhodium(III)-Catalyzed Cross-Dehydrogenative Coupling of Furan and Thiophene Derivatives
Nadine Kuhl, Dr. Matthew N. Hopkinson and Prof. Dr. Frank Glorius

Catalytic Asymmetric [4+2] Annulation Initiated by an Aza-Rauhut–Currier Reaction

Hypoiodite-Mediated Metal-Free Catalytic Aziridination of Alkenes

Angewchem

Hypoiodite-Mediated Metal-Free Catalytic Aziridination of Alkenes
Dr. Akira Yoshimura, Kyle R. Middleton, Chenjie Zhu, Prof. Dr. Victor N. Nemykin and Prof. Dr. Viktor V. Zhdankin

Cobalt-Catalyzed Direct Arylation and Benzylation

Catalyst-Free N-Arylation Using Unactivated Fluorobenzenes

Angewchem

Catalyst-Free N-Arylation Using Unactivated Fluorobenzenes
Dr. Frederik Diness and Prof. David P. Fairlie

Catalytic Generation of Zinc Carbenes from Alkynes: Zinc-Catalyzed Cyclopropanation

Angewchem

Catalytic Generation of Zinc Carbenes from Alkynes: Zinc-Catalyzed Cyclopropanation and SiH Bond Insertion Reactions
Dr. Rubén Vicente, Jesús González, Dr. Lorena Riesgo, Dr. Javier González and Dr. Luis A. López

Dehydrogenative Heck Reaction of Salicylaldehydes

Angewchem

Rhodium(III)-Catalyzed Dehydrogenative Heck Reaction of Salicylaldehydes
Dr. Zhuangzhi Shi, Nils Schröder and Prof. Dr. Frank Glorius

Enantioenriched Triarylmethanes by Stereospecific Cross-Coupling Reactions

Angewchem

Synthesis of Enantioenriched Triarylmethanes by Stereospecific Cross-Coupling Reactions
Buck L. H. Taylor, Michael R. Harris and Prof. Elizabeth R. Jarvo

One-Pot Approach to Installing Eight-Membered Rings onto Indoles

Angewchem

One-Pot Approach to Installing Eight-Membered Rings onto Indoles
Can Zhu, Xue Zhang, Xiongdong Lian and Prof. Dr. Shengming Ma

Double Hydrophosphination of Terminal Arylacetylenes

Jacs

Regioselective Double Hydrophosphination of Terminal Arylacetylenes Catalyzed by an Iron Complex
Masahiro Kamitani, Masumi Itazaki, Chihiro Tamiya, and Hiroshi Nakazawa

Ortho Trifluoromethylation of Arenes

Intermolecular Hydroamination of Unactivated Aliphatic Alkenes with Amides

Aerobic Aliphatic C–H Oxygenation Directed by an Amidine Moiety

Jacs

Copper-Catalyzed Aerobic Aliphatic C–H Oxygenation Directed by an Amidine Moiety
Yi-Feng Wang, Hui Chen, Xu Zhu, and Shunsuke Chiba

Conjugate Addition of Alkylboranes Catalyzed by a Copper–N-Heterocyclic Carbene

α-Aryl Carboxylic Acids from Styrene Derivatives and CO2

Gold(I)-Catalyzed Asymmetric Cyclopropenation of Internal Alkynes

Jcas

Gold(I)-Catalyzed Asymmetric Cyclopropenation of Internal Alkynes
John F. Briones and Huw M. L. Davies

Dehydrogenative Cross-Coupling of Heteroarenes

OL

Copper(II)-Mediated Dehydrogenative Cross-Coupling of Heteroarenes
Zhifeng Mao, Zhe Wang, Zhaoqing Xu, Fei Huang, Zhengkun Yu, and Rui Wang

arbonyl-Directed C–H and C–O Functionalization

OL

Short Synthesis of Alkyl-Substituted Acenes Using Carbonyl-Directed C–H and C–O Functionalization
Daiki Matsumura, Kentaroh Kitazawa, Seiya Terai, Takuya Kochi, Yutaka Ie, Masashi Nitani, Yoshio Aso, and Fumitoshi Kakiuchi

Transition-State Metal Aryl Bond Stability Determines Regioselectivity

Pd(II)-Catalyzed Primary-C(sp3)–H Acyloxylation at Room Temperature

OL

Pd(II)-Catalyzed Primary-C(sp3)–H Acyloxylation at Room Temperature
Raja K. Rit, M. Ramu Yadav, and Akhila K. Sahoo

Iron-Catalyzed Alkylations of Aryl Sulfamates and Carbamates

OL

Iron-Catalyzed Alkylations of Aryl Sulfamates and Carbamates
Amanda L. Silberstein, Stephen D. Ramgren, and Neil K. Garg

Sequential Borylation and Copper Catalysis

Intramolecular Hydroacylation

JOC

Cooperative Catalysis Approach to Intramolecular Hydroacylation
Evgeny V. Beletskiy, Ch. Sudheer, and Christopher J. Douglas

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