Review-Aerobic Oxidative C-H Functionalizations

Angewchem


Copper-Catalyzed Aerobic Oxidative C-H Functionalizations: Trends and Mechanistic Insights
Alison E. Wendlandt, Alison M. Suess and Shannon S. Stahl

Hair Reveals Source Of People’s Exposure To Mercury

C&EN


Hair Reveals Source Of People’s Exposure To Mercury:
Scientists can measure the total amount of mercury in a person’s blood, urine, or hair but it is difficult to determine how much mercury comes from different sources...... more on C&EN

Reaction of Aryl Iodides with ortho-Bromoanilines and Norbornene/Norbornadiene

Angewchem


Palladium-Catalyzed Reaction of Aryl Iodides with ortho-Bromoanilines and Norbornene/Norbornadiene: Unexpected Formation of Dibenzoazepine Derivatives
Dr. Nicola Della Ca', Dr. Giovanni Maestri, Prof. Max Malacria, Dr. Etienne Derat and Prof. Marta Catellani

Both Z- and E-α,β-Unsaturated Carbonyl Compounds

Angewchem


Heteropoly Compound Catalyzed Synthesis of Both Z- and E-α,β-Unsaturated Carbonyl Compounds
Dr. Masahiro Egi, Megumi Umemura, Takuya Kawai and Prof. Dr. Shuji Akai

Exception to the ortho Effect in Palladium/Norbornene Catalysis

Angewchem


Exception to the ortho Effect in Palladium/Norbornene Catalysis
Marie-Hélène Larraufie, Dr. Giovanni Maestri, Aurore Beaume, Dr. Étienne Derat, Dr. Cyril Ollivier, Prof. Louis Fensterbank, Prof. Christine Courillon, Dr. Emmanuel Lacôte, Prof. Marta Catellani and Prof. Max Malacria

Cycloaddition Reaction of Cyclopropyl Ketones with Alkynes

Cross-Coupling of Nonactivated Alkyl Halides with Alkynyl Grignard Reagents

Angewchem


Cross-Coupling of Nonactivated Alkyl Halides with Alkynyl Grignard Reagents: A Nickel Pincer Complex as the Catalyst
Dr. Oleg Vechorkin, Aurélien Godinat, Dr. Rosario Scopelliti and Prof. Dr. Xile Hu

Intramolecular (4+3) Cycloadditions of Allenedienes

Angewchem


Enantioselective Gold(I)-Catalyzed Intramolecular (4+3) Cycloadditions of Allenedienes
Isaac Alonso, Hélio Faustino, Dr. Fernando López and Prof. Dr. José L. Mascareñas

Oxidative C-O Coupling by Direct C-H Bond Activation of Formamides

Angewchem


Copper-Catalyzed Oxidative C-O Coupling by Direct C-H Bond Activation of Formamides: Synthesis of Enol Carbamates and 2-Carbonyl-Substituted Phenol Carbamates
G. Sathish Kumar, C. Uma Maheswari, R. Arun Kumar, Dr. M. Lakshmi Kantam and Dr. K. Rajender Reddy

Enantioselective Stetter Reactions of Enals

Angewchem


Enantioselective Stetter Reactions of Enals and Modified Chalcones Catalyzed by N-Heterocyclic Carbenes
Dr. Xinqiang Fang, Xingkuan Chen, Dr. Hui Lv and Prof. Dr. Yonggui Robin Chi

Hemilabile N,N Ligands in Nitrogen-Directed Iridium-Catalyzed Borylations

Angewchem


Use of Hemilabile N,N Ligands in Nitrogen-Directed Iridium-Catalyzed Borylations of Arenes
Dr. Abel Ros, Beatriz Estepa, Rocío López-Rodríguez, Dr. Eleuterio Álvarez, Prof. Rosario Fernández and Dr. José M. Lassaletta

Amination of Benzoxazoles and 1,3,4-Oxadiazoles

α-Amino Acid Amides: Ruthenium-Catalyzed Amination of α-Hydroxy Amides

Angewchem


Synthesis of α-Amino Acid Amides: Ruthenium-Catalyzed Amination of α-Hydroxy Amides
Dr. Min Zhang, Sebastian Imm, Sebastian Bähn, Dr. Helfried Neumann and Prof. Dr. Matthias Beller

Enantioselective Protonation via an Enamine Intermediate

Angewchem


Chiral Primary Amine Catalyzed Enantioselective Protonation via an Enamine Intermediate
Niankai Fu, Long Zhang, Jiuyuan Li, Prof. Sanzhong Luo and Prof. Jin-Pei Cheng

Asymmetric Synthesis of 2-Alkynyl Oxacycles

Angewchem


Palladium-Catalyzed Asymmetric Synthesis of 2-Alkynyl Oxacycles
David S. B. Daniels, Dr. Amber L. Thompson and Dr. Edward A. Anderson

Formation of Isoxazolidines by Enantioselective Copper-Catalyzed Annulation

Angewchem


Formation of Isoxazolidines by Enantioselective Copper-Catalyzed Annulation of 2-Nitrosopyridine with Allylstannanes
Indranil Chatterjee, Dr. Roland Fröhlich and Prof. Dr. Armido Studer

Characterization of Vinylgold Intermediates

Angewchem


Characterization of Vinylgold Intermediates: Gold-Mediated Cyclization of Acetylenic Amides
Dr. Olga A. Egorova, Hyewon Seo, Yonghwi Kim, Dr. Dohyun Moon, Prof. Young Min Rhee and Prof. Kyo Han Ahn

Decarboxylative Intramolecular Aziridination

Angewchem


Palladium-Catalyzed Decarboxylative Intramolecular Aziridination from 4H-Isoxazol-5-ones Leading to 1-Azabicyclo[3.1.0]hex-2-enes
Dr. Kazuhiro Okamoto, Tomohiro Oda, Sho Kohigashi and Prof. Dr. Kouichi Ohe

Hosomi–Sakurai Reactions with N,O-Aminals

Angewchem


A Catalytic Asymmetric Borono Variant of Hosomi–Sakurai Reactions with N,O-Aminals
Dr. Yi-Yong Huang, Dr. Ananya Chakrabarti, Naohide Morita, Dr. Uwe Schneider and Prof. Dr. Shū Kobayashi

Asymmetric N-H Insertion Reaction

Angewchem


Asymmetric N-H Insertion Reaction Cooperatively Catalyzed by Rhodium and Chiral Spiro Phosphoric Acids
Bin Xu, Prof. Shou-Fei Zhu, Xiu-Lan Xie, Jun-Jie Shen and Prof. Qi-Lin Zhou

Annulations of Aromatic Ketimines Induced by Directed C-H Activations

Cycloaddition/Hydrolytic Michael Addition/Retro-Aldol Reactions of Propargylic Esters

Direct Arylation of 6-Phenylpurine and 6-Arylpurine Nucleosides

Angewchem


Direct Arylation of 6-Phenylpurine and 6-Arylpurine Nucleosides by Ruthenium-Catalyzed C-H Bond Activation
Prof. Mahesh K. Lakshman, Dr. Ashoke C. Deb, Dr. Raghu Ram Chamala, Dr. Padmanava Pradhan and Dr. Ramendra Pratap

C-H Olefination of N-(2-Pyridyl)sulfonyl Anilines

Angewchem


PdII-Catalyzed C-H Olefination of N-(2-Pyridyl)sulfonyl Anilines and Arylalkylamines
Alfonso García-Rubia, Beatriz Urones, Dr. Ramón Gómez Arrayás and Prof. Dr. Juan C. Carretero

Asymmetric Reduction of Ketones by Phosphoric Acid Derived Catalysts

Angewchem


Asymmetric Reduction of Ketones by Phosphoric Acid Derived Catalysts
Dr. Zuhui Zhang, Pankaj Jain and Prof. Dr. Jon C. Antilla

Lithiation/Borylation/Suzuki–Miyaura Cross-Coupling Sequence

Angewchem


Continuous-Flow Synthesis of Biaryls Enabled by Multistep Solid-Handling in a Lithiation/Borylation/Suzuki–Miyaura Cross-Coupling Sequence
Dr. Wei Shu, Dr. Laurent Pellegatti, Dr. Matthias A. Oberli and Prof. Dr. Stephen L. Buchwald

Scandium-Catalyzed Silylation of Aromatic C-H Bonds

Angewchem


Scandium-Catalyzed Silylation of Aromatic C-H Bonds
Dr. Juzo Oyamada, Dr. Masayoshi Nishiura and Prof. Dr. Zhaomin Hou

An Alkyne Hydroacylation Route to Highly Substituted Furans

Angewchem


An Alkyne Hydroacylation Route to Highly Substituted Furans
Philip Lenden, Dr. David A. Entwistle and Dr. Michael C. Willis

Direct Asymmetric Hydrosilylation of Indoles

Angewchem


Direct Asymmetric Hydrosilylation of Indoles: Combined Lewis Base and Brønsted Acid Activation
You-Cai Xiao, Dr. Chao Wang, Yuan Yao, Prof. Dr. Jian Sun and Prof. Dr. Ying-Chun Chen

Aerobic Oxidative Coupling of Aryl Acetaldehydes with Anilines

Oxidative Cyclization of 2-Arylphenols to Dibenzofurans

Dehydrogenative Alkenylation of Cyclic Enaminones via the Fujiwara–Moritani Reaction

TEMPO Oxoammonium Salt-Mediated Dehydrogenative Povarov/Oxidation

Synthesis of (Z)-2-Bromovinyl Phenyl Ethers and Benzo[b]furans

Indole-Fused Scaffolds via Gold-Catalyzed Tandem Annulation

C–H Activation/C–S Cross-Coupling of Heterocycles with Thiols

JOC

Copper-Mediated C–H Activation/C–S Cross-Coupling of Heterocycles with Thiols
Sadananda Ranjit, Richmond Lee, Dodi Heryadi, Chao Shen, Ji’En Wu, Pengfei Zhang, Kuo-Wei Huang, and Xiaogang Liu

Oxidative Coupling of Benzyl and Allyl Alcohols with Alkynes

ortho-Quinone Methide Intermediates in Catalysis and Asymmetric Synthesis

Intramolecular C–H Activation/C–C Bond Formation

Removable 2-Pyridylsulfinyl Group- Coupling of Arene C–H Bonds

JOC

Palladium-Catalyzed Coupling of Arene C–H Bonds with Methyl- and Arylboron Reagents Assisted by the Removable 2-Pyridylsulfinyl Group
José A. Romero-Revilla, Alfonso Garcı́a-Rubia, Ramón Goméz Arrayás, M. Ángeles Fernández-Ibáñez, and Juan C. Carretero

Frustrated Lewis Pairs beyond the Main Group

Oxidant-Controlled Stereoselectivity in the Pd-Catalyzed Allylic Oxidation

Jacs

Oxidant-Controlled Stereoselectivity in the Pd-Catalyzed Allylic Oxidation of cis-Vinylsilanes
Christopher T. Check, William H. Henderson, Brenda C. Wray, Matthew J. Vanden Eynden, and James P. Stambuli

Silacarboxylic Acids as Efficient Carbon Monoxide Releasing Molecules

Ligand-Accelerated Cross-Coupling of C(sp2)–H Bonds with Arylboron Reagents

Jacs

Ligand-Accelerated Cross-Coupling of C(sp2)–H Bonds with Arylboron Reagents
Keary M. Engle, Peter S. Thuy-Boun, Michael Dang, and Jin-Quan Yu

C–H Bond Activation at Palladium(IV) Centers

Jacs

C–H Bond Activation at Palladium(IV) Centers
Joy M. Racowski, Nicholas D. Ball, and Melanie S. Sanford

Chiral Allene-Containing Phosphines in Asymmetric Catalysis

Jacs

Chiral Allene-Containing Phosphines in Asymmetric Catalysis
Feng Cai, Xiaotao Pu, Xiangbing Qi, Vincent Lynch, Akella Radha, and Joseph M. Ready

Dehydrogenative [4 + 2] Cycloaddition of 1,3-Dienes with Nitriles

Jacs

Nickel-Catalyzed Dehydrogenative [4 + 2] Cycloaddition of 1,3-Dienes with Nitriles
Masato Ohashi, Ippei Takeda, Masashi Ikawa, and Sensuke Ogoshi

Pd-Catalyzed Conversion of Aryl Triflates to Aryl Fluorides-mechanism

Jacs


Evidence for in Situ Catalyst Modification during the Pd-Catalyzed Conversion of Aryl Triflates to Aryl Fluorides
Thomas J. Maimone, Phillip J. Milner, Tom Kinzel, Yong Zhang, Michael K. Takase, and Stephen L. Buchwald

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