Innate C-H trifluoromethylation of heterocycles

PNAS

Innate C-H trifluoromethylation of heterocycles
Yining Ji, Tobias Brueckl, Ryan D. Baxter, Yuta Fujiwara, Ian B. Seiple, Shun Su, Donna G. Blackmond, and Phil S. Baran

Selective Catalytic C–H Alkylation of Alkenes with Alcohols

Science

Selective Catalytic C–H Alkylation of Alkenes with Alcohols
Dong-Hwan Lee, Ki-Hyeok Kwon, Chae S. Yi

Primary Alcohols from Terminal Olefins/Anti-Markovnikov Hydration

Science

Primary Alcohols from Terminal Olefins: Formal Anti-Markovnikov Hydration via Triple Relay Catalysis
Guangbin Dong, Peili Teo, Zachary K. Wickens, Robert H. Grubbs

Cross-coupling of C(sp2)–H Bonds and Alkyl–, Aryl–, and Vinyl–Boron Reagents

Direct Sequential C3 and C1 Arylation Reaction of Imidazo[1,5-a]pyridine

Enantioselective synthesis of 2-methyl indolines

Hydroacylation–Stetter–Rearrangement Cascade

Radical Cyclizations with Arylboronic Acids and Trifluoroborates

OL

Practical Radical Cyclizations with Arylboronic Acids and Trifluoroborates
Jonathan W. Lockner, Darryl D. Dixon, Rune Risgaard, and Phil S. Baran

Direct Acetoxylation of Arenes with Iodobenzene Diacetate

OL

Gold(III)-Catalyzed Direct Acetoxylation of Arenes with Iodobenzene Diacetate
Di Qiu, Zhitong Zheng, Fanyang Mo, Qing Xiao, Yu Tian, Yan Zhang, and Jianbo Wang

Electrophilic Addition of α-Diazoesters with Ketones

Jacs


New Electrophilic Addition of α-Diazoesters with Ketones for Enantioselective C–N Bond Formation
Wei Li, Xiaohua Liu, Xiaoyu Hao, Xiaolei Hu, Yangyang Chu, Weidi Cao, Song Qin, Changwei Hu, Lili Lin, and Xiaoming Feng

Oxidative Cycloaddition of Aromatic Amides to Alkynes

A Dehydrogenative Diels–Alder Reaction

Aerobic Dehydrogenation of Ketones

Synthesis of Dibenzodiazepines and Structural Analogues

(4+3) Cycloaddition Reaction of Furfuryl Cations

Angewchem


Scope and Mechanism of the (4+3) Cycloaddition Reaction of Furfuryl Cations
Dr. Johan M. Winne, Dr. Saron Catak, Prof. Dr. Michel Waroquier and Prof. Dr. Veronique Van Speybroeck

Heterocyclization and 1,2-Migration

Angewchem


Domino Reactions Consisting of Heterocyclization and 1,2-Migration—Redox-Neutral and Oxidative Transition-Metal Catalysis
Klaus-Daniel Umland, Adeline Palisse, Timm T. Haug and Prof. Dr. Stefan F. Kirsch

Enantioselective Hydroamination of Dienes by Gold(I)/Menthol Cooperative Catalysis

Angewchem


Regio- and Enantioselective Hydroamination of Dienes by Gold(I)/Menthol Cooperative Catalysis
Dr. Osamu Kanno, Dr. Wataru Kuriyama, Z. Jane Wang and Prof. F. Dean Toste

Phenanthridinones from N-Methoxybenzamides and Arenes

Tuning Chemoselectivity in Iron-Catalyzed Sonogashira-Type Reactions

Angewchem


Direct Asymmetric α Benzoyloxylation of Cyclic Ketones
Olga Lifchits, Dr. Nicolas Demoulin and Prof. Dr. Benjamin List

Construction of Substituted Benzene Rings by Pd-Catalyzed Direct Cross-Coupling

Metal-Free Diamination of Styrenes

Angewchem


Enantioselective Metal-Free Diamination of Styrenes
Dr. Caren Röben, Dr. José A. Souto, Yolanda González, Anton Lishchynskyi and Prof. Dr. Kilian Muñiz

Traceless Directing Groups for Formal meta-Selective Direct Arylation

Angewchem


Carboxylic Acids as Traceless Directing Groups for Formal meta-Selective Direct Arylation
Josep Cornella, Marika Righi and Dr. Igor Larrosa

Trifluoromethylation of Unactivated Olefins

Angewchem

Copper-Catalyzed Trifluoromethylation of Unactivated Olefins
Dr. Andrew T. Parsons and Prof. Dr. Stephen L. Buchwald

Enantioselective Formal [2+2] Cycloaddition of Ketenes and N-Sulfinylanilines

Direct Oxyphosphorylation of Alkenes with Dioxygen and H-Phosphonates

Domino Rhodium-Catalyzed Alkyne Arylation/Palladium-Catalyzed N Arylation

Nondirected C-H Oxygenation of Arenes

Angewchem


Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected C-H Oxygenation of Arenes
Dr. Marion H. Emmert, Amanda K. Cook, Yushu J. Xie and Prof. Melanie S. Sanford

Benzoxocines by an 8-endo-dig Cyclization

Angewchem


Gold(I)-Catalyzed Synthesis of Benzoxocines by an 8-endo-dig Cyclization
Dipl.-Chem. Kathrin Wittstein, Dr. Kamal Kumar and Prof. Dr. Herbert Waldmann

Enantioselective One-Pot Synthesis of Spirolactones

Angewchem


A Highly Enantioselective One-Pot Synthesis of Spirolactones by an Organocatalyzed Michael Addition/Cyclization Sequence
Dr. Silvia Sternativo, Antonella Calandriello, Dr. Ferdinando Costantino, Prof. Lorenzo Testaferri, Prof. Marcello Tiecco and Prof. Francesca Marini

Selective Monofluorination of Benzoic Acids Using a Practical Auxiliary

Angewchem


Palladium(II)-Catalyzed Selective Monofluorination of Benzoic Acids Using a Practical Auxiliary: A Weak-Coordination Approach
Kelvin S. L. Chan, Masayuki Wasa, Dr. Xisheng Wang and Prof. Dr. Jin-Quan Yu

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