Asymmetric Suzuki–Miyaura Coupling

Intermolecular Amination of Unactivated C H Bonds


Jun Pan, Mingjuan Su and Stephen L. Buchwald

Metal-free Cross-Amination of Unactivated Arenes

Intermolecular and Selective Synthesis of 2,4,5-Trisubstituted Oxazoles

Asymmetric Allylic Substitution of Allyl Phosphates


Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Aryl- and Alkenylboronates
Ryo Shintani, Keishi Takatsu, Momotaro Takeda and Tamio Hayashi

Palladium-Catalyzed Decarboxylative C(sp3)C(sp2) Coupling

Titanium-Mediated Amination of Grignard Reagents

Organocatalytic Asymmetric Biomimetic Transamination

Direct Ethynylation of C(sp3)–H Bonds in Aliphatic Carboxylic Acid Derivatives

2-Alkylation of Indoles by Norbornene-Mediated Regioselective Cascade

Dynamic Kinetic Asymmetric Transformation of Propargyl Esters


Chiral (Acyclic Diaminocarbene)Gold(I)-Catalyzed Dynamic Kinetic Asymmetric Transformation of Propargyl Esters
Yi-Ming Wang, Christian N. Kuzniewski, Vivek Rauniyar, Christina Hoong, and F. Dean Toste

Synthetic Versatility in C–H Oxidation

Direct Transformation of N,N-Dimethylformamide to −CN

Enantioselective Arylation of N-Tosylalkylaldimines


Highly Enantioselective Arylation of N-Tosylalkylaldimines Catalyzed by Rhodium-Diene Complexes
Zhe Cui, Hong-Jie Yu, Rui-Feng Yang, Wen-Yun Gao, Chen-Guo Feng, and Guo-Qiang Lin

Asymmetric Allylic Alkylations of Polynitrogen-Containing Aromatic Heterocycles

Asymmetric Synthesis of trans-γ-Lactams

Highly Efficient Hydrogen-Bonding Catalysis of the Diels–Alder Reaction

Pd-Catalyzed o-Alkenylation of Phenols


Silanol: A Traceless Directing Group for Pd-Catalyzed o-Alkenylation of Phenols
Chunhui Huang, Buddhadeb Chattopadhyay, and Vladimir Gevorgyan

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