Pyrenes by Twofold Hydroarylation of 2,6-Dialkynylbiphenyls

CHEMLETT


Synthesis of Pyrenes by Twofold Hydroarylation of 2,6-Dialkynylbiphenyls

Takanori Matsuda, Taisaku Moriya, Tsuyoshi Goya, and Masahiro Murakami

Coming Up - Insertion of an Alkene into an Ester

ANGEWCHEM


Insertion of an Alkene into an Ester: Intramolecular Oxyacylation Reaction of Alkenes through Acyl C–O Bond Activation
Giang T. Hoang, Venkata Jaganmohan Reddy, Huy H. K. Nguyen, Christopher J. Douglas*

Oxidant-Free Direct Coupling of Internal Alkynes and 2-Alkylpyridine

JACS


Oxidant-Free Direct Coupling of Internal Alkynes and 2-Alkylpyridine via Double C−H Activations by Alkylhafnium Complexes
Hayato Tsurugi, Koji Yamamoto, and Kazushi Mashima

Borylcyanocuprate in a One-Pot Carboboration by a Sequential Reaction with an Electron-Deficient Alkyne

ANGEWCHEM


Borylcyanocuprate in a One-Pot Carboboration by a Sequential Reaction with an Electron-Deficient Alkyne and an Organic Carbon Electrophile
Yuri Okuno, Makoto Yamashita and Kyoko Nozaki

Cross-Coupling of C-H Bonds with Grignard Reagents through Cobalt Catalysis

ANGEWCHEM


Direct Cross-Coupling of C-H Bonds with Grignard Reagents through Cobalt Catalysis
Bin Li, Zhen-Hua Wu, Yi-Fan Gu, Chang-Liang Sun, Bai-Quan Wang and Zhang-Jie Shi

Arylation of Electron-Deficient Arenes at Room Temperature

ANGEWCHEM

Palladium(II)-Catalyzed C-H Bond Arylation of Electron-Deficient Arenes at Room Temperature
Matthew J. Tredwell, Moises Gulias, Nadine Gaunt Bremeyer, Carin C. C. Johansson, Beatrice S. L. Collins and Matthew J. Gaunt

Enantioselective Catalytic Benzoyloxylation of 3-Aryloxindoles

ANGEWCHEM


Highly Enantioselective Catalytic Benzoyloxylation of 3-Aryloxindoles Using Chiral VAPOL Calcium Phosphate
Zuhui Zhang, Wenhua Zheng and Jon C. Antilla

Oxidative Olefination of C-H Bonds in Acetophenones and Benzamides

ANGEWCHEM


Rhodium-Catalyzed Oxidative Olefination of C-H Bonds in Acetophenones and Benzamides
Frederic W. Patureau, Tatiana Besset and Frank Glorius

Domino Condensation/S-Arylation/Heterocyclization Reactions

ANGEWCHEM


Domino Condensation/S-Arylation/Heterocyclization Reactions: Copper-Catalyzed Three-Component Synthesis of 2-N-Substituted Benzothiazoles
Dawei Ma, Xu Lu, Liu Shi, Hui Zhang, Yongwen Jiang and Xiangqian Liu

Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes

NATURECHEM

Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes
Ritu Ahuja, Benudhar Punji, Michael Findlater, Carolyn Supplee, William Schinski, Maurice Brookhart & Alan S. Goldman

An Atom-Economic Synthesis of Nitrogen Heterocycles from Alkynes

JACS

An Atom-Economic Synthesis of Nitrogen Heterocycles from Alkynes
Barry M. Trost, Jean-Philip Lumb, and Joseph M. Azzarelli

Ruthenium-Catalyzed Hydrohydroxyalkylation of 1,1-Disubstituted Allenes:

JACS

Amplification of Anti-Diastereoselectivity via Curtin−Hammett Effects in Ruthenium-Catalyzed Hydrohydroxyalkylation of 1,1-Disubstituted Allenes: Diastereoselective Formation of All-Carbon Quaternary Centers
Jason R. Zbieg, Emma L. McInturff, Joyce C. Leung, and Michael J. Krische

Generation and [3+2] Cycloaddition Reaction of α,β-Unsaturated Carbene Complex Intermediates

JACS

Platinum(II)-Catalyzed Generation and [3+2] Cycloaddition Reaction of α,β-Unsaturated Carbene Complex Intermediates for the Preparation of Polycyclic Compounds
Kodai Saito, Hideyuki Sogou, Takuya Suga, Hiroyuki Kusama, and Nobuharu Iwasawa

Enantioselective Total Synthesis of (+)-Salvileucalin B

JACS

Enantioselective Total Synthesis of (+)-Salvileucalin B
Sergiy Levin, Roger R. Nani, and Sarah E. Reisman

Carbocyclization of Dienyl Acetates to Construct Mutifunctionalized 3-Vinyl Cyclohexanol

JOC

Gold Catalyzed Carbocyclization of Dienyl Acetates to Construct Mutifunctionalized 3-Vinyl Cyclohexanol Derivatives
Li−Li Zhu, Ya-Hui Wang, Yu-Xin Zhang, Xiao-Xiao Li, Heng Liu, and Zili Chen

Straightforward Synthesis of Benzimidazole Derivatives in Water

JOC

Copper-Catalyzed Intramolecular C−N Bond Formation: A Straightforward Synthesis of Benzimidazole Derivatives in Water
Jinsong Peng, Min Ye, Cuijuan Zong, Fangyun Hu, Lingtong Feng, Xiaoyan Wang, Yufeng Wang, and Chunxia Chen

Transition-Metal-Free O-, S-, and N-Arylation of Alcohols, Thiols, Amides, Amines

JOC

Transition-Metal-Free O-, S-, and N-Arylation of Alcohols, Thiols, Amides, Amines, and Related Heterocycles
Rafael Cano, Diego J. Ramn, and Miguel Yus

Highly Diastereo- and Enantioselective Copper(I)-Catalyzed Henry Reaction

JOC

A Highly Diastereo- and Enantioselective Copper(I)-Catalyzed Henry Reaction Using a Bis(sulfonamide)−Diamine Ligand
Wei Jin, Xincheng Li, and Boshun Wan

Enyne Cycloisomerization Approach to the Triple Reuptake Inhibitor GSK1360707F

JOC

An Enyne Cycloisomerization Approach to the Triple Reuptake Inhibitor GSK1360707F
Nicole M. Deschamps, Vassil I. Elitzin, Bing Liu, Mark B. Mitchell, Matthew J. Sharp, and Elie A. Tabet

Oxidative Coupling of Unactivated Alkenes via C−H Activation

OL

Rh(III)-Catalyzed Oxidative Coupling of Unactivated Alkenes via C−H Activation
Andy S. Tsai, Mikael Brasse, Robert G. Bergman, and Jonathan A. Ellman

Carbon−Sulfur Bond Formation Protocol in Water

OL


An Efficient Copper-Catalyzed Carbon−Sulfur Bond Formation Protocol in Water
Fang Ke, Yanyang Qu, Zhaoqiong Jiang, Zhengkai Li, Di Wu, and Xiangge Zhou

Direct Sulfoximination of Azoles and Polyfluoroarenes

OL

Copper-Catalyzed Direct Sulfoximination of Azoles and Polyfluoroarenes under Ambient Conditions
Mitsuru Miyasaka, Koji Hirano, Tetsuya Satoh, Rafal Kowalczyk, Carsten Bolm, and Masahiro Miura

Cross-Coupling of Polyfluoroarenes with Simple Arenes

OL

Palladium-Catalyzed Cross-Coupling of Polyfluoroarenes with Simple Arenes
Hu Li, Jia Liu, Chang-Liang Sun, Bi-Jie Li, and Zhang-Jie Shi

NHC−Cu-Catalyzed Enantioselective Conjugate Additions of Si-Containing Vinylaluminums

JACS

Formation of Vinyl-, Vinylhalide- or Acyl-Substituted Quaternary Carbon Stereogenic Centers through NHC−Cu-Catalyzed Enantioselective Conjugate Additions of Si-Containing Vinylaluminums to β-Substituted Cyclic Enones
Tricia L. May, Jennifer A. Dabrowski, and Amir H. Hoveyda

Cycloaddition of Acyl Azides and 1-Alkynes-Formation of 2,5-Disubstituted Oxazoles

JACS

Regioselective Formation of 2,5-Disubstituted Oxazoles Via Copper(I)-Catalyzed Cycloaddition of Acyl Azides and 1-Alkynes
Israel Cano, Eleuterio Alvarez, M. Carmen Nicasio, and Pedro J. Perez

Silicon-Mediated Carbon−Carbon Bond-Forming Reactions of Unactivated Amides

JACS

Catalytic Silicon-Mediated Carbon−Carbon Bond-Forming Reactions of Unactivated Amides
Shu Kobayashi, Hiroshi Kiyohara, and Miyuki Yamaguchi

Gallium (III)-catalysed bromocyanation of alkynes

CHEMCOMM

Gallium (III)-catalysed bromocyanation of alkynes: regio- and stereoselective synthesis of β-bromo-α,β-unsaturated nitriles
Masahito Murai, Ryo Hatano, Sachie Kitabata and Kouichi Ohe

Markovnikov-type additions of E–H bonds to alkynes

CHEM.COMM

A new oxapalladacycle generated via ortho C–H activation of phenylphosphinic acid: an efficient catalyst for Markovnikov-type additions of E–H bonds to alkynes
Qing Xu, Ruwei Shen, Yutaka Ono, Ritsuko Nagahata, Shigeru Shimada, Midori Goto and Li-Biao Han

Reversal of Selectivity in Gold-Catalyzed Cyclizations of 3,3-Disubstituted 1,4-Diynes

OL


Reversal of Selectivity in Gold-Catalyzed Cyclizations of 3,3-Disubstituted 1,4-Diynes
Roman Rottinger, Juliane Leutzow, Michael Wilsdorf, Kristina Wilckens, and Constantin Czekelius

[{Au(IPr)}2(μ-OH)]X Complexes

CHEM.EUR.J

[{Au(IPr)}2(μ-OH)]X Complexes: Synthetic, Structural and Catalytic Studies
Rubén S. Ramón, Sylvain Gaillard, Albert Poater, Luigi Cavallo, Alexandra M. Z. Slawin and Steven P. Nolan

Asymmetric Vinylogous and Bisvinylogous Mukaiyama Aldol Reactions

ANGEWCHEM

Disulfonimide-Catalyzed Asymmetric Vinylogous and Bisvinylogous Mukaiyama Aldol Reactions
Lars Ratjen, Pilar García-García, Frank Lay, Michael Edmund Beck and Benjamin List

Copper-Catalyzed Tandem Reactions of 1-(2-Iodoary)-2-yn-1-ones with Isocyanides

OL

Copper-Catalyzed Tandem Reactions of 1-(2-Iodoary)-2-yn-1-ones with Isocyanides for the Synthesis of 4-Oxo-indeno[1,2-b]pyrroles
Qian Cai, Fengtao Zhou, Tianfeng Xu, Liangbing Fu, and Ke Ding

Borylation of Aryl and Alkenyl Carbamates

CHEM.EUR.J


Borylation of Aryl and Alkenyl Carbamates through Ni-Catalyzed C-O Activation
Kun Huang, Da-Gang Yu, Shu-Fang Zheng, Zhen-Hua Wu and Zhang-Jie Shi

Oxidative Coupling of Alkylamides with Arenes

JOC

Iron-Catalyzed Oxidative Coupling of Alkylamides with Arenes through Oxidation of Alkylamides Followed by Friedel−Crafts Alkylation
Eiji Shirakawa, Nanase Uchiyama, and Tamio Hayashi

Direct Arylation of Heteroarenes with Aryl Mesylates

CHEM.EUR.J

Palladium-Catalyzed Direct Arylation of Heteroarenes with Aryl Mesylates
Chau Ming So, Chak Po Lau and Fuk Yee Kwong

Allylic C−OH Functionalization for Efficient Synthesis of Functionalized Allylsilanes

JACS

Palladium-Catalyzed Allylic C−OH Functionalization for Efficient Synthesis of Functionalized Allylsilanes
Nicklas Selander, Jennifer R. Paasch, and Kalman J. Szabo

Regioselectivity-Switchable Hydroarylation of Styrenes

JACS

Regioselectivity-Switchable Hydroarylation of Styrenes
Ke Gao and Naohiko Yoshikai

Cobalt-Catalyzed ortho-Alkylation of Secondary Benzamide with Alkyl Chloride

JACS

Cobalt-Catalyzed ortho-Alkylation of Secondary Benzamide with Alkyl Chloride through Directed C−H Bond Activation
Quan Chen, Laurean Ilies, and Eiichi Nakamura

Enantioselective Synthesis of Diarylethanes

JACS

Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Alkyl Ethers: Enantioselective Synthesis of Diarylethanes
Buck L. H. Taylor, Elizabeth C. Swift, Joshua D. Waetzig, and Elizabeth R. Jarvo

Radical Cyclizations Terminated by Ir-Catalyzed Hydrogen Atom Transfer

JACS

Radical Cyclizations Terminated by Ir-Catalyzed Hydrogen Atom Transfer
Andreas Gansauer, Matthias Otte, and Lei Shi

Enantioselective Intermolecular Hydroarylation of Allenes with Indoles

CHEM.ASIAN.J


Gold(I)-Catalyzed Enantioselective Intermolecular Hydroarylation of Allenes with Indoles and Reaction Mechanism by Density Functional Theory Calculations
Ming-Zhong Wang, Cong-Ying Zhou, Zhen Guo, Ella Lai-Ming Wong, Man-Kin Wong and Chi-Ming Che

Review - Alkenylation Reactions of Heteroarenes

SYNTHESIS


Rossi, Renzo; Bellina, Fabio; Lessi, Marco:
Alkenylation Reactions of Heteroarenes by Transition-Metal Catalysts

Review - Catalytic C–H functionalization by metalloporphyrins

CHEM.SOC.REV


Catalytic C–H functionalization by metalloporphyrins: recent developments and future directions
Hongjian Lu and X. Peter Zhang

Review - Visible light photoredox catalysis: applications in organic synthesis

CHEM.SOC.REV


Visible light photoredox catalysis: applications in organic synthesis
Jagan M. R. Narayanam and Corey R. J. Stephenson

Review - Diastereotopos-differentiating C–H activation reactions at methylene groups

CHEM.SOC.REV

Diastereotopos-differentiating C–H activation reactions at methylene groups
Pavel Herrmann and Thorsten Bach

Review -Enzymatic functionalization of carbon–hydrogen bonds

CHEM.SOC.REV


Enzymatic functionalization of carbon–hydrogen bonds
Jared C. Lewis, Pedro S. Coelho and Frances H. Arnold

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