Synthesis of Propiolic Acids via Copper-Catalyzed Insertion of Carbon Dioxide into the C-H Bond of Terminal Alkynes

Decarbonylative Coupling of Aldehydes and Norbornenes

Synthesis of 3-Alkyl-3-hydroxyindolin-2-ones

Packed-Bed Reactors for Continuous-Flow C-N Cross-Coupling

Pyranoquinolines, Pyranoquinolinones, and Isocumarins


Iodine-Mediated Solvent-Controlled Selective Electrophilic Cyclization and Oxidative Esterification of o-Alkynyl Aldehydes: An Easy Access to Pyranoquinolines, Pyranoquinolinones, and Isocumarins
Akhilesh K. Verma, Vineeta Rustagi, Trapti Aggarwal, and Amit P. Singh

Direct Arylation of Azines


Rh(I)-Catalyzed Direct Arylation of Azines
Ashley M. Berman, Robert G. Bergman, and Jonathan A. Ellman

Direct Carboxylation of Arenes


Direct Carboxylation of Arenes and Halobenzenes with CO2 by the Combined Use of AlBr3 and R3SiCl
Koji Nemoto, Hiroki Yoshida, Naoki Egusa, Naoya Morohashi, and Tetsutaro Hattori

3-Substituted 2-Pyrones


A Concise Access to 3-Substituted 2-Pyrones.
Frdric Frbault, Maria Teresa Oliveira, Eckhard Wstefeld, and Nuno Maulide

Addition of Salicylaldehydes to Homoallylic Sulfides

Intramolecular O-H Insertion:Cyclic Ethers

Cobalt-Mediated, Enantioselective Synthesis of C2 and C1 Dienes


Cobalt-Mediated, Enantioselective Synthesis of C2 and C1 Dienes
W. Christopher Boyd, Mark R. Crimmin, Lauren E. Rosebrugh, Jennifer M. Schomaker, Robert G. Bergman, and F. Dean Toste

Enantioenriched Synthesis of Cyclopropenes with a Quaternary Stereocenter, Versatile Building Blocks

Palladium-Catalyzed Aminosulfonylation of Aryl Halides

Intramolecular Hydroamination/Cyclization of Aminoalkenes Catalyzed by Ln[N(SiMe3)2]3 Grafted onto Periodic Mesoporous Silicas

Enantioselective Desymmetrization of Cyclopropenes by Hydroacylation

Dienyl Homoallyl Alcohols via Palladium Catalyzed Ene-Type Reaction of Aldehydes with 1,3-Dienes

Hydrogen-Bonding-Promoted Oxidative Addition and Regioselective Arylation of Olefins with Aryl Chlorides

Capturing H2S(g) by In Situ-Prepared Ultradispersed Metal Oxide Particles in an Oilsand-Packed Bed Column

Safety - NaBH4 in DMA or DMF

ORG.PRO.RES.DEV
Safety Evaluation of Sodium Borohydride in Dimethylacetamide
Sumio Shimizu, Hiroshi Osato, Yoshiaki Imamura, and Yuusuke Satou

Control of Product Selectivity by a Styrene Additive in Ruthenium-Catalyzed C−H Arylation

OL

Control of Product Selectivity by a Styrene Additive in Ruthenium-Catalyzed C−H Arylation
Shun Hiroshima, Daiki Matsumura, Takuya Kochi, and Fumitoshi Kakiuchi

The [4+2], not [2+2], Mechanism Occurs in the Gold-Catalyzed Intramolecular Oxygen Transfer Reaction of 2-Alkynyl-1,5-Diketones

Selective Catalytic Oxidation of Glycerol to Dihydroxyacetone

Enantioselective Hydrogenation with Chiral Frustrated Lewis Pairs

REVIEW:Oxetanes as Versatile Elements in Drug Discovery and Synthesis

ANGEWCHEM

Oxetanes as Versatile Elements in Drug Discovery and Synthesis
Johannes A. Burkhard, Georg Wuitschik, Mark Rogers-Evans, Klaus Müller and Erick M. Carreira

Pd(OAc)2-Catalyzed Oxidative C−H/C−H Cross-Coupling of Electron-Deficient Polyfluoroarenes with Simple Arenes

Nickel-Catalyzed, Directing-Group-Assisted [2+2+2] Cycloaddition of Imine and Alkynes

C-2 Arylation of Piperidines through Directed Transition-Metal-Catalyzed sp3 C-H Activation

CHEM.EUR.J

C-2 Arylation of Piperidines through Directed Transition-Metal-Catalyzed sp3 C-H Activation
Hana Prokopcová, Sheba D. Bergman, Karel Aelvoet, Veerle Smout, Wouter Herrebout, Benjamin Van der Veken, Lieven Meerpoel and Bert U. W. Maes

Palladium/Nickel-Cocatalyzed Cycloaddition of 1,3-Dehydro-o-Carborane with Alkynes. Facile Synthesis of C,B-Substituted Carboranes

A Multiligand Based Pd Catalyst for C−N Cross-Coupling Reactions

Generation of benzyne from benzoic acid using C–H activation

Highly active and recyclable silica gel-supported palladium catalyst for mild cross-coupling reactions of unactivated heteroaryl chlorides

Carbonates: eco-friendly solvents for palladium-catalysed direct arylation of heteroaromatics

GREENCHEM

Jia Jia Dong, Julien Roger, Cécile Verrier, Thibaut Martin, Ronan Le Goff, Christophe Hoarau and Henri Doucet

Facile, solvent and ligand free iron catalyzed direct functionalization of N-protected tetrahydroisoquinolines and isochroman

Gold(I)-Catalyzed Cycloisomerization of 2-Fluoroalk-3-yn-1-ones: Synthesis of 2,5-Substituted 3-Fluorofurans

Iron-Facilitated Direct Oxidative C−H Transformation of Allylarenes or Alkenes to Alkenyl Nitriles

Cu(I)−Amido Complexes in the Ullmann Reaction: Reactions of Cu(I)−Amido Complexes with Iodoarenes with and without Autocatalysis by CuI

Highly Brominated Antimicrobial Metabolite


Highly Brominated Antimicrobial Metabolites from a Marine Pseudoalteromonas sp.
Domonkos Fehr, Russell Barlow, Jesse McAtee, and Thomas K. Hemscheidt

Fischer Indole Synthesis with Organozinc Reagents

ANGEWCHEM

 Fischer Indole Synthesis with Organozinc Reagents
Benjamin A. Haag, Zhi-Guang Zhang, Jin-Shan Li and Paul Knochel

Primary and Secondary Aminophosphines as Novel P-Stereogenic Building Blocks for Ligand Synthesis

Primary and Secondary Aminophosphines as Novel P-Stereogenic Building Blocks for Ligand Synthesis
Marc Revés, Catalina Ferrer, Thierry León, Sean Doran, Pablo Etayo, Anton Vidal-Ferran, Antoni Riera and Xavier Verdaguer

Synthesis of α-Fluoro Acetals and α-Fluoro Ketones from Alkynes

Gold-Catalyzed Synthesis of α-Fluoro Acetals and α-Fluoro Ketones from Alkynes
Teresa de Haro and Cristina Nevado

Enantioselective Fluorination of α-Chloro-β-keto Esters


Catalytic Enantioselective Fluorination of α-Chloro-β-keto Esters in the Presence of Chiral Nickel Complexes
Seung Hee Kang and Dae Young Kim

REVIEW - α-Fluorinated Amino Acid Derivatives


Stereoselective Synthesis of α-Fluorinated Amino Acid Derivatives
Atsushi Tarui, Kazuyuki Sato, Masaaki Omote, Itsumaro Kumadaki and Akira Ando

REVIEW - Enatioselective Trifluoromethylation

ADV.SYN.CAT


Yan Zheng and Jun-An Ma

REVIEW - Enantioselective Fluorination Reactions


Sylvain Lectard, Yoshitaka Hamashima and Mikiko Sodeoka

Organometallics with Cancer Cell Cytotoxicity


Organometallic Osmium Arene Complexes with Potent Cancer Cell Cytotoxicity
Ying Fu, Abraha Habtemariam, Ana M. Pizarro, Sabine H. van Rijt, David J. Healey, Patricia A. Cooper, Steven D. Shnyder, Guy J. Clarkson, and Peter J. Sadler

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